{"id":"W2043690521","doi":"10.1021/ic051004d","title":"Examination of the Bonding in Binary Transition-Metal Monophosphides MP (M = Cr, Mn, Fe, Co) by X-Ray Photoelectron Spectroscopy","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":467,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; X-ray photoelectron spectroscopy; Transition metal; Valence (chemistry); Binding energy; Metal; Core electron; Spectral line; Electronic structure; Valence electron; Photoemission spectroscopy; Band gap; Chemical bond; Crystallography; Analytical Chemistry (journal); Atomic physics; Electron; Computational chemistry; Condensed matter physics; Nuclear magnetic resonance","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000748505,0.0002080727,0.0001479269,0.0002348405,0.000164897,0.0002786867,0.0002809629,0.0003477003,0.001192281],"category_scores_gemma":[0.0003616583,0.0001693449,0.00007306041,0.0001786802,0.0002120072,0.0002443535,0.0002582264,0.0003208912,0.0001448765],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002094489,"about_ca_system_score_gemma":0.00009324733,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004566383,"about_ca_topic_score_gemma":0.0005515552,"domain_scores_codex":[0.9999166,0.000007098286,0.00000441702,0.00001968449,0.00003653242,0.00001575238],"domain_scores_gemma":[0.9998957,0.00003128078,0.00002706202,0.000006273148,0.00002292035,0.0000168524],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007549348,0.00002156173,0.0009817726,0.00009254578,0.000008809671,0.0001255046,0.00004265756,0.0002052358,0.9955615,0.0003035672,0.00005232244,0.002529113],"study_design_scores_gemma":[0.00001266387,0.0002110759,0.01551697,0.00001082724,0.00001696393,0.0003633221,0.00007591012,0.002893221,0.9789366,0.0001817483,0.001774549,0.000006271292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981731,0.0002147461,0.0005444633,0.00001824428,0.000002589533,0.000006784261,0.00006176071,0.00001492896,0.0009632809],"genre_scores_gemma":[0.9974595,0.0001860301,0.001357397,0.00001835378,0.000002053537,0.00001586033,0.0001206117,0.000008708906,0.0008316716],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001192281,"threshold_uncertainty_score":0.003988564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003747196835218209,"score_gpt":0.2185625381530202,"score_spread":0.2148153413178019,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}