{"id":"W2043775573","doi":"10.1107/s1600536805032216","title":"A hybrid bidentate and tridentate ruthenium(II) complex incorporating triazine and polypyridine carbene ligands","year":2005,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Carbene; Chemistry; Denticity; Ligand (biochemistry); Acetonitrile; Ruthenium; Triazine; Nitrile; Steric effects; Pyridine; Medicinal chemistry; Ring (chemistry); Stereochemistry; Polymer chemistry; Crystal structure; Crystallography; Organic chemistry; Catalysis; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002053765,0.0006145895,0.0007219705,0.0002397911,0.0005144892,0.0001505695,0.0001870301,0.0003171892,0.0007292156],"category_scores_gemma":[0.0001547042,0.0005880463,0.0001830838,0.0003920823,0.0003579871,0.0003632641,0.0003922069,0.0007157673,2.205514e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000116116,"about_ca_system_score_gemma":0.00007739964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000176314,"about_ca_topic_score_gemma":0.0002605075,"domain_scores_codex":[0.9967262,0.00002186422,0.001239124,0.001037142,0.0004798075,0.0004959318],"domain_scores_gemma":[0.9977356,0.00007582068,0.0009716605,0.00070876,0.0001463481,0.0003618403],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001078491,0.00009535361,0.005565973,0.0001310897,0.0002103907,0.0001381609,0.000140616,0.000009452272,0.990432,0.00000288215,0.0002990828,0.002867161],"study_design_scores_gemma":[0.01281492,0.0006489758,0.03003294,0.0005317094,0.001783744,0.07998633,0.002314326,0.002848462,0.5709023,0.005635908,0.2876683,0.004831983],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968742,0.0006509391,0.00002866017,0.0009524742,0.000284829,0.0001726906,0.0002886868,0.0003250673,0.0004224548],"genre_scores_gemma":[0.9951671,0.000724951,0.0008049328,0.000212351,0.001797783,0.000006365869,0.0008364866,0.0001028905,0.0003470771],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4195296,"threshold_uncertainty_score":0.9996571,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008137592010166634,"score_gpt":0.235889531673676,"score_spread":0.2277519396635093,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}