{"id":"W2043775573","doi":"10.1107/s1600536805032216","title":"A hybrid bidentate and tridentate ruthenium(II) complex incorporating triazine and polypyridine carbene ligands","year":2005,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Carbene; Chemistry; Denticity; Ligand (biochemistry); Acetonitrile; Ruthenium; Triazine; Nitrile; Steric effects; Pyridine; Medicinal chemistry; Ring (chemistry); Stereochemistry; Polymer chemistry; Crystal structure; Crystallography; Organic chemistry; Catalysis; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001414119,0.0003257686,0.0005353339,0.0001713561,0.0001845233,0.0005794673,0.0007743926,0.0004694385,0.001028288],"category_scores_gemma":[0.0001662091,0.0002728941,0.0001300995,0.0002269057,0.0002448955,0.0003763359,0.0002982796,0.0003280975,0.0004382615],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000582469,"about_ca_system_score_gemma":0.0002218655,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006226386,"about_ca_topic_score_gemma":0.001110873,"domain_scores_codex":[0.9997645,0.00002623212,0.00001382346,0.00008095905,0.0000610362,0.00005343815],"domain_scores_gemma":[0.9999071,0.00001357505,0.00002200752,0.00001392359,0.000009986589,0.0000333504],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001845117,0.00003413228,0.00007014866,0.00007190669,0.00001136279,0.0000611697,0.00002138459,0.0002143603,0.9970688,0.0003821591,0.00009371364,0.001786303],"study_design_scores_gemma":[0.00008633917,0.0003393196,0.0003978613,0.000003992686,0.00002286825,0.0002104265,0.00001321715,0.001513256,0.9935277,0.00003357093,0.003839134,0.00001220694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835719,0.001363106,0.00986142,0.0001303856,0.00004638148,0.00009802979,0.0002984121,0.0004222092,0.004208002],"genre_scores_gemma":[0.9862584,0.0004067631,0.00901464,0.0000500545,0.00001051848,0.00004961474,0.0003093537,0.00004989103,0.003850779],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001028288,"threshold_uncertainty_score":0.004226148,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008137592010166634,"score_gpt":0.235889531673676,"score_spread":0.2277519396635093,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}