{"id":"W2043838519","doi":"10.1002/ejoc.200801025","title":"Cesium (<i>Z</i>)‐2‐Carbomethoxyethenethiolate: A Reagent for the Preparation of (<i>Z</i>)‐2‐Carbomethoxyethenyl Thioethers Including Selected Cysteine and Homocysteine Derivatives","year":2008,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Reagent; Electrophile; Caesium; Base (topology); Substitution reaction; Alkyl; Electrophilic substitution; Enantiomer; Conjugate; Cysteine; Medicinal chemistry; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003699649,0.0005084731,0.0002021948,0.0002590619,0.0001972087,0.0002243349,0.0003630148,0.0003773121,0.001322873],"category_scores_gemma":[0.0002626044,0.0001952602,0.0001584853,0.0002026661,0.0002462592,0.0003612706,0.000323799,0.0003822673,0.001012539],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002407188,"about_ca_system_score_gemma":0.0003031052,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002731096,"about_ca_topic_score_gemma":0.0004402635,"domain_scores_codex":[0.999859,0.00003552722,0.00001540877,0.00002868728,0.00004279172,0.00001860943],"domain_scores_gemma":[0.9998879,0.00001915203,0.00002444679,0.0000228213,0.00002168695,0.00002394632],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002806564,0.000005686068,0.00003369856,0.00004221195,0.000003721532,0.00006437572,0.00001370675,0.00003524556,0.998068,0.0002215521,0.00006244867,0.001421268],"study_design_scores_gemma":[0.00000937374,0.00006736348,0.0001862228,0.000002275572,0.000005045833,0.0002345396,0.00000439971,0.00008043039,0.9954512,0.00003058198,0.003924869,0.00000364958],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8920985,0.007968798,0.084737,0.0005647324,0.0003068556,0.0002808177,0.0007606404,0.0006969778,0.01258567],"genre_scores_gemma":[0.9337769,0.004940453,0.04650486,0.0001753883,0.00005832224,0.0001288726,0.001202376,0.0001707568,0.01304213],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001322873,"threshold_uncertainty_score":0.004425406,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03111595381259042,"score_gpt":0.2630563380009867,"score_spread":0.2319403841883963,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}