{"id":"W2043944154","doi":"10.1021/ol403495e","title":"Diazirines as Potent Electrophilic Nitrogen Sources: Application to the Synthesis of Pyrazoles","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Electrophile; Nitrogen; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0000650379,0.0001262451,0.0001469962,0.00003624648,0.00009325054,0.00003651427,0.0003507544,0.00004488395,0.00107995],"category_scores_gemma":[0.000116628,0.00008768913,0.00008945008,0.0001554112,0.00004687843,0.00005462504,0.00004810133,0.00008006228,0.001031706],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006394357,"about_ca_system_score_gemma":0.00002216346,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004003337,"about_ca_topic_score_gemma":0.00001070463,"domain_scores_codex":[0.9991761,0.00001059697,0.0002064608,0.0002087068,0.0001949317,0.0002032293],"domain_scores_gemma":[0.9991122,0.0001437498,0.00009965366,0.0005396166,0.00003817728,0.00006660801],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00000305422,0.00003133305,0.0007966805,0.00001543915,0.00005619353,2.976797e-7,0.00012296,0.00001016521,0.9846952,0.00004513182,0.002532777,0.0116908],"study_design_scores_gemma":[0.00004702919,0.000004191497,0.001245393,0.00001389067,0.00005624496,0.00001320753,0.0003181294,0.00002494527,0.9928599,0.0001276488,0.005179095,0.000110353],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792985,0.00006229689,0.0002658827,0.01930099,0.00001937141,0.000138207,0.000004687628,0.00005006158,0.0008600015],"genre_scores_gemma":[0.9982043,0.00002209891,0.00004051877,0.001210185,0.0001801411,0.0002249651,0.000005301181,0.00002905133,0.00008344279],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01890579,"threshold_uncertainty_score":0.9998332,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00425129585457854,"score_gpt":0.1859540949091036,"score_spread":0.1817027990545251,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}