{"id":"W2043981198","doi":"10.1021/ol702152e","title":"Copper-Catalyzed Alkene Aziridination with <i>N</i>-Tosyloxycarbamates","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":107,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Intramolecular force; Alkene; Pyridine; Intermolecular force; Catalysis; Allylic rearrangement; Copper; Combinatorial chemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001795446,0.0003833174,0.0002241533,0.0001513637,0.0001350578,0.0002356909,0.0003333531,0.0001661305,0.000759966],"category_scores_gemma":[0.00025929,0.0001300678,0.0001324307,0.0001645957,0.0002177536,0.0001750171,0.0002231028,0.0002300169,0.0002002384],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003513545,"about_ca_system_score_gemma":0.0001461021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007625544,"about_ca_topic_score_gemma":0.001028017,"domain_scores_codex":[0.9998493,0.00002731491,0.0000106328,0.00003044747,0.00004063767,0.00004168571],"domain_scores_gemma":[0.999931,0.00001164524,0.00001992032,0.00001119047,0.00001018373,0.00001608446],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001515229,0.00002145653,0.0002296972,0.00009122724,0.00001472757,0.0001538828,0.0000847725,0.0002365823,0.9928583,0.0007437065,0.0001256758,0.005288478],"study_design_scores_gemma":[0.0000137322,0.0000760745,0.0002788853,0.000002294444,0.000008268371,0.00009014129,0.000008292227,0.0002369405,0.9982388,0.00003362483,0.001010266,0.000002806518],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883599,0.001997794,0.004025592,0.00004108224,0.00002469547,0.00002875578,0.00007020267,0.00006924174,0.005382541],"genre_scores_gemma":[0.9969473,0.0006002355,0.001078088,0.000008842285,0.000005389651,0.000008525028,0.0000480879,0.00001205395,0.001291551],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007625544,"threshold_uncertainty_score":0.002549291,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006719657602282887,"score_gpt":0.2037218275949452,"score_spread":0.1970021699926623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}