{"id":"W2043981198","doi":"10.1021/ol702152e","title":"Copper-Catalyzed Alkene Aziridination with <i>N</i>-Tosyloxycarbamates","year":2007,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":107,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Intramolecular force; Alkene; Pyridine; Intermolecular force; Catalysis; Allylic rearrangement; Copper; Combinatorial chemistry; Medicinal chemistry; Polymer chemistry; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001777091,0.0001662347,0.0001560893,0.00005540693,0.0001153581,0.00005095553,0.0001781065,0.00007194043,0.0008906166],"category_scores_gemma":[0.00004273887,0.0001378212,0.00005373121,0.0001924892,0.00006698874,0.0001435459,0.00002481616,0.0001303715,0.0002219812],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000142284,"about_ca_system_score_gemma":0.00002945452,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004374487,"about_ca_topic_score_gemma":0.00002984157,"domain_scores_codex":[0.9989511,0.0000050347,0.0002030015,0.0002710705,0.0002613456,0.0003083909],"domain_scores_gemma":[0.9992704,0.00012182,0.0001005649,0.0003772139,0.00003686831,0.0000930661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001633807,0.00004375646,0.002524691,0.0000181227,0.00005159711,0.00002286426,0.0001147867,0.000001238645,0.9934821,0.0000828245,0.001813536,0.001828219],"study_design_scores_gemma":[0.000435448,0.000005619611,0.001797173,0.00002914531,0.00005345996,0.00007936662,0.000387329,0.000007302507,0.9915031,0.000007339137,0.005489748,0.00020502],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892247,0.00004521658,0.0006710684,0.002761218,0.00007734761,0.00004708418,0.000006173184,0.0001616098,0.007005596],"genre_scores_gemma":[0.9984279,0.00001057277,0.0002690922,0.0007187536,0.0002114078,0.000007141329,0.00006241687,0.00004515319,0.0002475399],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009203235,"threshold_uncertainty_score":0.9751627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006719657602282887,"score_gpt":0.2037218275949452,"score_spread":0.1970021699926623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}