{"id":"W2043996384","doi":"10.1021/ic051412h","title":"Phosphorescent Cu(I) Complexes of 2-(2‘-pyridylbenzimidazolyl)benzene:  Impact of Phosphine Ancillary Ligands on Electronic and Photophysical Properties of the Cu(I) Complexes","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":216,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Phosphine; Phosphorescence; Copper; Ligand (biochemistry); Luminescence; Photochemistry; Crystallography; Crystal structure; Fluorescence; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001324632,0.0003089519,0.0002540767,0.00008927856,0.0001257653,0.000377951,0.0003865053,0.0003027981,0.001135361],"category_scores_gemma":[0.000304167,0.0001586957,0.00006700325,0.0001437787,0.000198209,0.0001873037,0.0002485285,0.0002615945,0.000214425],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004054451,"about_ca_system_score_gemma":0.000124314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001331265,"about_ca_topic_score_gemma":0.001699616,"domain_scores_codex":[0.9998354,0.00004585255,0.000006717984,0.00002950798,0.00003383613,0.00004867624],"domain_scores_gemma":[0.999891,0.00002309529,0.0000279224,0.000006780944,0.00001745399,0.00003371809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003227068,0.0000234796,0.0001197587,0.0001101112,0.000007980735,0.00003427681,0.00004442696,0.0001861701,0.9975346,0.0001570568,0.00009326213,0.001366105],"study_design_scores_gemma":[0.00003293108,0.0002203425,0.0007244661,0.000006667583,0.00001135344,0.00007113737,0.00002138609,0.0008951108,0.9968652,0.000016603,0.001129911,0.00000477079],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954992,0.001465303,0.001299347,0.00005113664,0.00001184766,0.000008826258,0.00007525924,0.0001093681,0.001479768],"genre_scores_gemma":[0.9974309,0.0004719516,0.000952322,0.00002210807,0.000003378508,0.000008237715,0.00008107205,0.00001745903,0.001012711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001331265,"threshold_uncertainty_score":0.003798127,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01726707883914963,"score_gpt":0.24050736922872,"score_spread":0.2232402903895704,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}