{"id":"W2044111369","doi":"10.1063/1.4900512","title":"Direct experimental determination of spectral densities of molecular complexes","year":2014,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Air Force Office of Scientific Research","keywords":"Fluorescence; Rhodopsin; Molecule; Spectral line; Electron transfer; Electron density; Analytical Chemistry (journal); Solvent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001119417,0.00009170097,0.0002905709,0.00001025978,0.00002205203,0.000004053652,0.0001567972,0.00001492533,0.00002216251],"category_scores_gemma":[0.00001031346,0.00006144324,0.0001578846,0.00005835697,0.0001963571,0.00005339279,0.00004078473,0.0001084049,5.099851e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001358216,"about_ca_system_score_gemma":0.00001025733,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001370704,"about_ca_topic_score_gemma":3.272858e-8,"domain_scores_codex":[0.9993306,0.00003673774,0.0002864914,0.00004587115,0.0001964292,0.0001038941],"domain_scores_gemma":[0.9992824,0.0001684839,0.0003399819,0.00009215858,0.0000892536,0.00002776277],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005956197,0.0001291639,0.0002030857,0.00001003644,0.00005111718,1.023769e-7,0.000349811,0.00001100201,0.9907368,0.007938723,0.00005969586,0.0004508474],"study_design_scores_gemma":[0.0002634272,0.00009877837,0.00005048354,0.00003284718,0.0000586966,0.000001296747,0.0002161056,0.0001719853,0.9769626,0.0220665,0.00001777764,0.00005952024],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917009,0.0001143715,0.005227389,0.00003419906,0.00003531431,0.00002936767,0.000004738299,0.00000238283,0.002851307],"genre_scores_gemma":[0.9991117,0.000001894657,0.0006066674,0.00001514028,0.0002523566,5.063803e-7,0.00000150541,0.000007088332,0.000003183704],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01412778,"threshold_uncertainty_score":0.2505583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009993858269202285,"score_gpt":0.2592948903523094,"score_spread":0.2493010320831071,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}