{"id":"W2044722916","doi":"10.1002/cjce.21750","title":"Photoswitchable azobenzene‐ and stilbene‐based chromophores bearing terminal nitro groups: Synthesis, thermal and photochemical properties","year":2012,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Science Council","keywords":"Azobenzene; Chromophore; Photochemistry; Photochromism; Methylene; Isomerization; Liquid crystal; Differential scanning calorimetry; Chemistry; Materials science; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000712317,0.0001995384,0.000122426,0.00009716496,0.00006190292,0.0001219569,0.0001037123,0.00015406,0.0007924727],"category_scores_gemma":[0.0001048632,0.00007855519,0.0001201672,0.0001013831,0.0001247549,0.0001698036,0.00006946902,0.0002073116,0.0001458519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001687583,"about_ca_system_score_gemma":0.00008754223,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002958699,"about_ca_topic_score_gemma":0.0007736791,"domain_scores_codex":[0.9999503,0.000007466427,0.000003079088,0.00001147283,0.00001527611,0.0000124699],"domain_scores_gemma":[0.9999175,0.0000204947,0.00002573843,0.00000624679,0.00001079862,0.00001917526],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001724947,0.000005083565,0.00003936504,0.00001195927,0.000001279466,0.000008291647,0.00000321386,0.00003256115,0.9995549,0.0000208989,0.000003131845,0.0003019151],"study_design_scores_gemma":[0.000002830729,0.00009786908,0.0007390167,0.000001350282,0.000003904278,0.00002477788,0.000004799154,0.0002836171,0.9985824,0.00000494602,0.0002528839,0.000001625645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978243,0.0004583775,0.001078247,0.00001284522,0.000005552231,0.000007476604,0.00006068731,0.00002007378,0.0005323975],"genre_scores_gemma":[0.9977639,0.0002969829,0.001130387,0.00001038218,0.000002886814,0.000007801045,0.00007657769,0.00000878778,0.0007023272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007924727,"threshold_uncertainty_score":0.002651095,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01198016832802461,"score_gpt":0.185327618587716,"score_spread":0.1733474502596914,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}