{"id":"W2044762131","doi":"10.1002/chem.200600653","title":"Scope and Mechanistic Insights into the Use of Tetradecyl(trihexyl)phosphonium Bistriflimide: A Remarkably Selective Ionic Liquid Solvent for Substitution Reactions","year":2006,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University; McMaster University Medical Centre","funders":"Natural Sciences and Engineering Research Council of Canada; McMaster University","keywords":"Phosphonium; Ionic liquid; Chemistry; Substitution reaction; Chemoselectivity; Phosphinate; Electrophile; Elimination reaction; Carbocation; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000370703,0.0005247846,0.0002399608,0.0003293793,0.0001633243,0.0004032624,0.0004361491,0.0003733779,0.001457985],"category_scores_gemma":[0.0002553212,0.0001773006,0.0002681465,0.0002002451,0.000393874,0.0006320908,0.0003299293,0.000519776,0.000601829],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002827246,"about_ca_system_score_gemma":0.0003433277,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003725032,"about_ca_topic_score_gemma":0.0005216462,"domain_scores_codex":[0.9998624,0.00002968655,0.00001284134,0.00002572138,0.00003346565,0.00003574358],"domain_scores_gemma":[0.9998939,0.00004456611,0.00002296562,0.00001127283,0.00001503766,0.00001221348],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001625314,0.00005979948,0.0004477873,0.0002059965,0.000007995825,0.000301414,0.00006211227,0.0008042879,0.9794231,0.001325691,0.00004631379,0.01715304],"study_design_scores_gemma":[0.000009051379,0.0002535153,0.0003993648,0.000009216462,0.00001091216,0.000611103,0.00002481617,0.0005538408,0.9949538,0.0001531364,0.003014751,0.000006490431],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9329468,0.0137062,0.03415658,0.0003644874,0.00002827085,0.0001522346,0.0002851162,0.0003827161,0.01797761],"genre_scores_gemma":[0.9668722,0.01232631,0.01760159,0.0001271734,0.0000238206,0.00005780199,0.0002728625,0.00007199093,0.002646217],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001457985,"threshold_uncertainty_score":0.004877448,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02266555332565333,"score_gpt":0.2158355073218627,"score_spread":0.1931699539962094,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}