{"id":"W2045020342","doi":"10.15278/isms.2014.te11","title":"A PEPTIDE CO SOLVENT IN A CHIRALITY INDUCTION MODEL SYSTEM: BROADBAND ROTATIONAL SPECTROSCOPY OF THE 2,2,2-TRIFLUOROETHANOL- -PROPYL ENE OXIDE ADDUCT","year":2014,"lang":"en","type":"article","venue":"","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chirality (physics); Chemistry; Diastereomer; Hydrogen bond; Dimer; Adduct; Spectroscopy; Rotational spectroscopy; Photochemistry; Crystallography; Molecule; Stereochemistry; Organic chemistry; Chiral symmetry breaking; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00010663,0.0001865629,0.0001567895,0.00009193365,0.0001348956,0.0001397164,0.0001526585,0.0001804857,0.0006370072],"category_scores_gemma":[0.0001420381,0.00008308628,0.00006472706,0.0001055464,0.0002180988,0.0002039309,0.0001155595,0.000300836,0.0001157169],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001163825,"about_ca_system_score_gemma":0.0001303384,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004473161,"about_ca_topic_score_gemma":0.0004207264,"domain_scores_codex":[0.9999293,0.00001218087,0.000002389659,0.0000208775,0.00002012885,0.00001511691],"domain_scores_gemma":[0.9999322,0.00001865056,0.00002266432,0.000006496974,0.000009169606,0.00001083194],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005948594,0.000009868986,0.0001297331,0.00001607876,0.000002498809,0.00003357572,0.00001503858,0.0001684876,0.9990374,0.00009860232,0.00001121915,0.000418103],"study_design_scores_gemma":[0.00001156248,0.0002272765,0.001072995,0.000002445139,0.000006024631,0.00005579097,0.00001951124,0.002431893,0.995656,0.00003391376,0.0004778975,0.000004731648],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981407,0.00007150866,0.001369825,0.00001398237,0.000003164346,0.00000485391,0.00003012903,0.00001389919,0.0003518226],"genre_scores_gemma":[0.9978771,0.0001093364,0.001444027,0.00001056431,0.000002631832,0.000006871411,0.00008005032,0.000009586193,0.0004599146],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006370072,"threshold_uncertainty_score":0.002130985,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009560453330784327,"score_gpt":0.2462071745653539,"score_spread":0.2366467212345696,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}