{"id":"W2045020342","doi":"10.15278/isms.2014.te11","title":"A PEPTIDE CO SOLVENT IN A CHIRALITY INDUCTION MODEL SYSTEM: BROADBAND ROTATIONAL SPECTROSCOPY OF THE 2,2,2-TRIFLUOROETHANOL- -PROPYL ENE OXIDE ADDUCT","year":2014,"lang":"en","type":"article","venue":"","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chirality (physics); Chemistry; Diastereomer; Hydrogen bond; Dimer; Adduct; Spectroscopy; Rotational spectroscopy; Photochemistry; Crystallography; Molecule; Stereochemistry; Organic chemistry; Chiral symmetry breaking; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002664653,0.000230199,0.0003223644,0.00005984878,0.00009961337,0.00002887968,0.0003213102,0.0001849,0.0001878613],"category_scores_gemma":[0.00007193773,0.0001682091,0.000170196,0.0001766507,0.00009799222,0.00008989617,0.00005783186,0.0003899263,0.000003652769],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002120488,"about_ca_system_score_gemma":0.0001270624,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004584439,"about_ca_topic_score_gemma":0.0002738857,"domain_scores_codex":[0.9982629,0.00008387506,0.0004844569,0.0003940141,0.0004684287,0.0003063296],"domain_scores_gemma":[0.9990359,0.00002668619,0.0002379859,0.0005666251,0.00006430575,0.00006848066],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008802032,0.00005996852,0.003814475,0.0002296412,0.00002959308,0.000001219367,0.0001357594,0.002778471,0.9793009,0.01329407,0.0002064821,0.00006142299],"study_design_scores_gemma":[0.0007321649,0.00002308871,0.005033169,0.0001230579,0.00002705802,0.00001734248,0.0001462475,0.0202087,0.9703491,0.003089962,0.00006589411,0.0001842436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9701468,0.00005467467,0.006391125,0.0001635151,0.00008090778,0.0001883348,0.00002836403,0.00005571845,0.02289054],"genre_scores_gemma":[0.9950632,0.000005335834,0.003942787,0.00006165357,0.0001101326,0.00003623823,0.00002509979,0.00002198353,0.0007336103],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02491634,"threshold_uncertainty_score":0.6859367,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009560453330784327,"score_gpt":0.2462071745653539,"score_spread":0.2366467212345696,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}