{"id":"W2045516220","doi":"10.1063/1.2349606","title":"Technique for determination of accurate heat capacities of volatile, powdered, or air-sensitive samples using relaxation calorimetry","year":2006,"lang":"en","type":"article","venue":"Review of Scientific Instruments","topic":"thermodynamics and calorimetric analyses","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Differential scanning calorimetry; Heat capacity; Calorimetry; Materials science; Relaxation (psychology); Physical property; Benzoic acid; Analytical Chemistry (journal); Atmospheric temperature range; Thermodynamics; Chromatography; Chemistry; Composite material; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005469363,0.0001511184,0.0004786585,0.0002328866,0.00009974679,0.00001264195,0.0001664128,0.00008981424,0.00007098004],"category_scores_gemma":[0.0002491616,0.0001253008,0.0001934245,0.0006726788,0.0003045933,0.0001778189,0.00004208518,0.0000593336,4.530913e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001122945,"about_ca_system_score_gemma":0.0001275518,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000463006,"about_ca_topic_score_gemma":0.00001796113,"domain_scores_codex":[0.9983272,0.00003238791,0.0008354573,0.0002584509,0.0003812359,0.0001652803],"domain_scores_gemma":[0.9982966,0.0001004703,0.000703106,0.0002960667,0.0005765511,0.00002717208],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005962962,0.0001445758,0.0005870823,0.01147322,0.00006341683,5.377004e-7,0.00006469565,0.00001337343,0.9625382,0.0006974341,0.0000618857,0.02429596],"study_design_scores_gemma":[0.0003083108,0.00004005743,0.0002281345,0.005289513,0.0002147441,0.00000665615,0.0001811108,0.009807962,0.9830033,0.0005506807,0.0002103426,0.000159255],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9842796,0.001229057,0.01262083,0.000006796408,0.0001623982,0.0004445878,0.0006160868,0.00001526912,0.0006253127],"genre_scores_gemma":[0.987893,0.000518296,0.01101376,0.000006072502,0.00002459823,0.00001847167,0.0002324894,0.00001500451,0.0002782468],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0241367,"threshold_uncertainty_score":0.5109617,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03706719907260782,"score_gpt":0.2987218649022432,"score_spread":0.2616546658296354,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}