{"id":"W2045532578","doi":"10.1039/b506178d","title":"Amino acid conjugates of 1,1′-diaminoferrocene. Synthesis and chiral organization","year":2005,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Synthon; Chemistry; Ferrocene; Intramolecular force; Stereochemistry; Amino acid; Chirality (physics); Nuclear magnetic resonance spectroscopy; Conjugate; Alanine; Peptide; Combinatorial chemistry; Electrochemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005891054,0.0003056372,0.0002996488,0.00002028745,0.0001280345,0.00003897735,0.000348571,0.0002946029,0.004072595],"category_scores_gemma":[0.0002579365,0.0003362732,0.00007224496,0.0003303389,0.0002100316,0.0000904041,0.0001484769,0.0001719428,0.00003691631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007117186,"about_ca_system_score_gemma":0.00009051767,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003070083,"about_ca_topic_score_gemma":6.201696e-7,"domain_scores_codex":[0.998552,0.000006694829,0.0004063189,0.0005044031,0.0002218331,0.0003087904],"domain_scores_gemma":[0.9988627,0.00004282984,0.0002057843,0.0005621407,0.0001502301,0.000176257],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000008511992,0.0001358586,0.0006332192,0.0004629357,0.00005642168,0.000004297949,0.00007397676,3.89092e-7,0.9970566,0.00002950886,0.0001387222,0.001399536],"study_design_scores_gemma":[0.0003409357,0.00000379916,0.000121336,0.00007655565,0.00009903159,0.00008132218,0.0001593291,0.00006497476,0.9974508,0.00004613042,0.001217249,0.0003385074],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9833829,0.001007058,0.003082079,0.0005258174,0.00001250747,0.00006113492,0.00008348624,0.0001933031,0.01165176],"genre_scores_gemma":[0.9976573,0.000151825,0.0006740741,0.00006762451,0.0001708938,0.00001733129,0.0001635764,0.00006679088,0.001030609],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01427442,"threshold_uncertainty_score":0.9999089,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00490418417252923,"score_gpt":0.19721705082906,"score_spread":0.1923128666565308,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}