{"id":"W2045619159","doi":"10.1021/ie0493614","title":"Effects of Operating Variables on the Product Distribution and Reaction Pathways in the Oxidative Degradation of CO<sub>2</sub>-Loaded Aqueous MEA−MDEA Blends during CO<sub>2</sub>Absorption from Flue Gas Streams","year":2005,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Carbon Dioxide Capture Technologies","field":"Engineering","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Amine gas treating; Degradation (telecommunications); Aqueous solution; Solvent; Chemical engineering; Nuclear chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002508223,0.0006970948,0.0003989572,0.0002418737,0.0001729239,0.0004341919,0.0002979994,0.0004056618,0.0008641136],"category_scores_gemma":[0.0004629677,0.0002775966,0.0002563044,0.0002372226,0.0002932235,0.0004146081,0.0002074249,0.0004407268,0.0002024707],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003432612,"about_ca_system_score_gemma":0.0002221648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001241426,"about_ca_topic_score_gemma":0.002439764,"domain_scores_codex":[0.9997855,0.00002356268,0.00002327977,0.00006207056,0.00005120223,0.00005441651],"domain_scores_gemma":[0.9997751,0.0000845385,0.00005920663,0.00001169323,0.00003780298,0.00003167837],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004100488,0.00001795338,0.0004254903,0.00005422761,0.00001000813,0.00005135773,0.00003330975,0.0002472163,0.9978971,0.00001295168,0.00001231999,0.0008279925],"study_design_scores_gemma":[0.000004764802,0.000203773,0.002887115,0.00000365259,0.00001464,0.00002189743,0.00003590573,0.000761744,0.9958638,0.000006459079,0.0001904797,0.000005886456],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984671,0.0003208872,0.0007221226,0.0000161786,0.000007958054,0.00001245915,0.0001541747,0.00003593545,0.0002632043],"genre_scores_gemma":[0.9979711,0.0003896802,0.001021732,0.00001657723,0.000004149485,0.00002678244,0.000130003,0.0000233025,0.0004166328],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001241426,"threshold_uncertainty_score":0.002890766,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02615608296656936,"score_gpt":0.2450521072935972,"score_spread":0.2188960243270278,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}