{"id":"W2045647923","doi":"10.1021/om900022n","title":"Reactivity of SiMe<sub>3</sub>- and SnR<sub>3</sub>-Functionalized Bis(7-azaindol-1-yl)methane with [PtR<sub>2</sub>(μ-SMe<sub>2</sub>)]<sub><i>n</i></sub>(R = Me, Ph) and the Resulting Pt(II) and Pt(IV) Complexes","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Electrophile; Medicinal chemistry; Reactivity (psychology); Metathesis; Bond cleavage; Stereochemistry; Methane; Platinum; Cleavage (geology); Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001251698,0.0002574378,0.0001849707,0.00009056519,0.00008537068,0.0001429662,0.0002118296,0.0003077214,0.001519995],"category_scores_gemma":[0.0001941848,0.0001631313,0.0001066582,0.00009470885,0.0001837352,0.0001745021,0.0001800762,0.0002874358,0.0003099101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002613869,"about_ca_system_score_gemma":0.0001281615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005132461,"about_ca_topic_score_gemma":0.001151931,"domain_scores_codex":[0.9999065,0.00002111214,0.000004097692,0.00001568623,0.00002799997,0.00002458465],"domain_scores_gemma":[0.9999388,0.00001539002,0.00002016601,0.000004744846,0.00000688224,0.00001390025],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001371598,0.000005505929,0.0001693724,0.00003299838,0.00000592758,0.00004091275,0.0000290003,0.0001682917,0.9986885,0.00006490636,0.00003124928,0.0006261229],"study_design_scores_gemma":[0.000004656991,0.0000961503,0.0007921836,0.00000146117,0.000003999296,0.0000686829,0.00001240055,0.0006272903,0.997841,0.00001087837,0.0005380079,0.000003244151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965558,0.0004949422,0.001298229,0.00004143211,0.000008497479,0.0000089877,0.00008528017,0.00004821179,0.001458652],"genre_scores_gemma":[0.9964207,0.0002667086,0.001366881,0.00002876012,0.00000231492,0.000009978883,0.000147672,0.00001371675,0.001743201],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001519995,"threshold_uncertainty_score":0.005084932,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01338393525266654,"score_gpt":0.2315368133043124,"score_spread":0.2181528780516458,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}