{"id":"W2045668538","doi":"10.1021/ic801990g","title":"Trigonal-Bipyramidal Metal Cyanide Complexes: A Versatile Platform for the Systematic Assessment of the Magnetic Properties of Prussian Blue Materials","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Prussian blue; Crystallography; Trigonal bipyramidal molecular geometry; Cyanide; Supramolecular chemistry; Molecule; Magnetism; Metal; Ion; Inorganic chemistry; Crystal structure; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006850391,0.00021891,0.0005264848,0.00002143639,0.0001750676,0.00008146577,0.0009833724,0.00008384103,0.001635033],"category_scores_gemma":[0.0003361781,0.0001235843,0.0001298411,0.0001771518,0.0002795235,0.0001027502,0.0001478789,0.00008658726,0.000004952231],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009571132,"about_ca_system_score_gemma":0.0002458736,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006153608,"about_ca_topic_score_gemma":0.000009082362,"domain_scores_codex":[0.9980142,0.00006851419,0.0008615147,0.0002588123,0.0005335695,0.0002633821],"domain_scores_gemma":[0.998165,0.0002824762,0.0006172234,0.0007152261,0.0001788373,0.00004126627],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002538704,0.00008315185,0.000008768561,0.004820224,0.00002595896,2.634508e-7,0.0003291551,0.00002904943,0.993942,0.0005864148,0.0001169868,0.00003266535],"study_design_scores_gemma":[0.0005170637,0.00009291301,0.0007418325,0.0009350099,0.0001542772,0.00002473135,0.0005355175,0.0004787545,0.9959142,0.0004085974,0.00005236948,0.0001447167],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965981,0.0005561791,0.0001883686,0.0005314872,0.0002814978,0.001315268,0.0001563497,0.00004012783,0.0003326173],"genre_scores_gemma":[0.9988434,0.000005865063,0.0004785457,0.00005598195,0.00008937463,0.0001121111,0.000005950593,0.00001752236,0.0003912043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003885214,"threshold_uncertainty_score":0.9992776,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0208874876415381,"score_gpt":0.2499606914149249,"score_spread":0.2290732037733868,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}