{"id":"W2045668538","doi":"10.1021/ic801990g","title":"Trigonal-Bipyramidal Metal Cyanide Complexes: A Versatile Platform for the Systematic Assessment of the Magnetic Properties of Prussian Blue Materials","year":2009,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Prussian blue; Crystallography; Trigonal bipyramidal molecular geometry; Cyanide; Supramolecular chemistry; Molecule; Magnetism; Metal; Ion; Inorganic chemistry; Crystal structure; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001411104,0.0004322506,0.0002743474,0.0001896637,0.0001511904,0.0002716753,0.0005729743,0.0002563931,0.00053881],"category_scores_gemma":[0.0001830495,0.0001733959,0.00008847452,0.000248219,0.000230436,0.0002087736,0.0003284743,0.0003975046,0.000239972],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003747842,"about_ca_system_score_gemma":0.0001572589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008570293,"about_ca_topic_score_gemma":0.001537208,"domain_scores_codex":[0.9998324,0.0000339468,0.000009928876,0.00004034644,0.00006210319,0.00002126777],"domain_scores_gemma":[0.9998988,0.00001324848,0.00002813048,0.00001553195,0.00002050722,0.000023747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006292175,0.00000745682,0.00007248386,0.00004540489,0.000005948759,0.00001860806,0.00001671774,0.0001297032,0.9981019,0.000119142,0.00004502484,0.001374696],"study_design_scores_gemma":[0.00001550069,0.0001219805,0.0006715022,0.00000299389,0.000009439204,0.00008599828,0.00001401394,0.000802541,0.9966847,0.00002610723,0.00155883,0.000006397322],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9872949,0.001342782,0.008487186,0.00008925598,0.00001789185,0.00009503036,0.0003845338,0.0002537867,0.002034751],"genre_scores_gemma":[0.9797734,0.001196368,0.01688816,0.0000467324,0.000007424984,0.00008048963,0.0005166315,0.00007692719,0.001413883],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008570293,"threshold_uncertainty_score":0.002719223,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0208874876415381,"score_gpt":0.2499606914149249,"score_spread":0.2290732037733868,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}