{"id":"W2045743544","doi":"10.1021/jp073425h","title":"Adsorbate−Induced Diffusion of Ag and Au Atoms Out of the Cores of Ag@Au, Au@Ag, and Ag@AgI Core−Shell Nanoparticles","year":2007,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Defence Research and Development Canada","funders":"","keywords":"Nanoparticle; Materials science; Shell (structure); Diffusion; Dithiol; Chemical physics; Metal; Chemical engineering; Nanotechnology; Chemistry; Thermodynamics; Metallurgy; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00144711,0.0001725976,0.000458752,0.00001959724,0.0001109804,0.00002390868,0.0007424568,0.00006220654,0.00002772226],"category_scores_gemma":[0.0004885321,0.00009642426,0.00008696918,0.0001631678,0.001349173,0.0001591416,0.0004055912,0.0001536481,0.000001769522],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006994894,"about_ca_system_score_gemma":0.0002327878,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001258881,"about_ca_topic_score_gemma":0.00001550683,"domain_scores_codex":[0.9981788,0.00004919049,0.0006466005,0.0001721765,0.0006499949,0.000303221],"domain_scores_gemma":[0.9977775,0.0004512318,0.001042459,0.0003737178,0.0002236184,0.000131425],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002380017,0.0001603623,0.0006892944,0.000285992,0.00001033509,0.000002128621,0.002790672,0.00001972947,0.9955202,0.00005336806,0.00001489942,0.0002150021],"study_design_scores_gemma":[0.0004837086,0.0001343315,0.008407405,0.0002564817,0.0000807546,0.00005075392,0.0005358795,0.0001400596,0.9878071,0.001993444,0.000006972628,0.0001031311],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9992797,0.00007813583,0.00002023931,0.0000931688,0.0001931688,0.00008447305,0.00002110967,0.000005181052,0.0002247758],"genre_scores_gemma":[0.999633,0.00001833792,0.00005965924,0.00001661713,0.0002261825,5.840744e-7,3.612519e-7,0.00001038173,0.00003492706],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00771811,"threshold_uncertainty_score":0.4971084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01834066747452624,"score_gpt":0.2721393502693044,"score_spread":0.2537986827947782,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}