{"id":"W2045778822","doi":"10.1021/om020013g","title":"Synthesis, Characterization, and Thermochemistry of (<i>η</i><sup>1</sup>-C<sub>13</sub>H<sub>9</sub>)Mn(CO)<sub>5</sub> and (<i>η</i><sup>5</sup>-C<sub>13</sub>H<sub>9</sub>)Mn(CO)<sub>3</sub>","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Chemistry; Thermochemistry; Crystal structure; X-ray crystallography; Manganese; Chemical reaction kinetics; Crystallography; Characterization (materials science); Inorganic chemistry; Chemical kinetics; Kinetics; Diffraction; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001092859,0.0001042154,0.00007335243,0.0001303208,0.0001412391,0.0001994096,0.0001228819,0.0001531502,0.001145072],"category_scores_gemma":[0.0002965287,0.000100069,0.0000722939,0.0000907953,0.0001565409,0.0001503144,0.00008006983,0.0001377267,0.0002725046],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004244354,"about_ca_system_score_gemma":0.0002348087,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001978725,"about_ca_topic_score_gemma":0.00372373,"domain_scores_codex":[0.9999378,0.000005243712,0.000003236901,0.00001611927,0.00002423997,0.0000134699],"domain_scores_gemma":[0.9998934,0.0000123515,0.00003153333,0.00001256132,0.00003165328,0.00001840369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004909022,0.000008466703,0.0003172941,0.00002182331,0.000001691549,0.00002536386,0.00002265984,0.0001151708,0.9967909,0.0001446001,0.00004912286,0.002453855],"study_design_scores_gemma":[0.000001929989,0.0000542389,0.002006328,0.000001668232,0.00000379322,0.00006291666,0.000009285742,0.0003219157,0.9959255,0.00001861921,0.001591595,0.000002182647],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906163,0.0004642063,0.005648308,0.0000456838,0.00001164357,0.00002217466,0.0003038048,0.00004090319,0.002846871],"genre_scores_gemma":[0.9937889,0.0001960969,0.002397486,0.00001672291,0.000002030407,0.000008783609,0.0003971498,0.00001629487,0.003176499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001978725,"threshold_uncertainty_score":0.003934383,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006972653767581535,"score_gpt":0.1906391036463944,"score_spread":0.1836664498788129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}