{"id":"W2045778822","doi":"10.1021/om020013g","title":"Synthesis, Characterization, and Thermochemistry of (<i>η</i><sup>1</sup>-C<sub>13</sub>H<sub>9</sub>)Mn(CO)<sub>5</sub> and (<i>η</i><sup>5</sup>-C<sub>13</sub>H<sub>9</sub>)Mn(CO)<sub>3</sub>","year":2002,"lang":"en","type":"article","venue":"Organometallics","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Chemistry; Thermochemistry; Crystal structure; X-ray crystallography; Manganese; Chemical reaction kinetics; Crystallography; Characterization (materials science); Inorganic chemistry; Chemical kinetics; Kinetics; Diffraction; Nanotechnology","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.001530664,0.005302694,0.005214617,0.001179944,0.001663293,0.001334964,0.003389491,0.004542876,0.0004727275],"category_scores_gemma":[0.001745713,0.005836545,0.002183263,0.003374635,0.002689587,0.001593913,0.001924943,0.004383944,0.0004403033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001224956,"about_ca_system_score_gemma":0.0008102999,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002821412,"about_ca_topic_score_gemma":0.0000578836,"domain_scores_codex":[0.9795313,0.0006911108,0.005008201,0.006162287,0.003684731,0.004922399],"domain_scores_gemma":[0.9853868,0.00129731,0.003209583,0.005465462,0.001456827,0.003184032],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005575278,0.001528135,0.0007871882,0.002582961,0.002083967,0.0004467493,0.001458478,0.0002987389,0.9378887,0.0001654676,0.001603432,0.05059868],"study_design_scores_gemma":[0.004936071,0.0002744423,0.001249621,0.001176939,0.001967264,0.001085546,0.0005501179,0.005647198,0.9735849,0.000896003,0.002813665,0.00581824],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9840905,0.003593205,0.0008414131,0.000868141,0.0004851311,0.002017913,0.004777395,0.001171533,0.00215475],"genre_scores_gemma":[0.9706748,0.01861162,0.0002090087,0.0013056,0.001936397,0.0005752803,0.004733034,0.001810254,0.0001440133],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04478044,"threshold_uncertainty_score":0.9997017,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006972653767581535,"score_gpt":0.1906391036463944,"score_spread":0.1836664498788129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}