{"id":"W2045847047","doi":"10.1002/chin.200111047","title":"ChemInform Abstract: Migrating Alkynes in Vinylidene Carbenoids: An Unprecedented Route to Polyynes.","year":2001,"lang":"en","type":"article","venue":"ChemInform","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Service (business); Combinatorial chemistry; Business; Marketing","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001756064,0.0004594279,0.0004177626,0.0002054129,0.0001141443,0.0001409281,0.0005580964,0.0003425407,0.004206962],"category_scores_gemma":[0.0001702601,0.0004868742,0.0001350142,0.0005097781,0.00003036163,0.000779564,0.0001532695,0.0004518222,0.0002338012],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006021881,"about_ca_system_score_gemma":0.0001264473,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008058572,"about_ca_topic_score_gemma":0.00294709,"domain_scores_codex":[0.9973888,9.300968e-8,0.0008074876,0.0005036885,0.0005142845,0.0007855961],"domain_scores_gemma":[0.9983302,0.00005804676,0.0002502168,0.0007674221,0.0001475911,0.0004464899],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001159151,0.0001186715,0.001262733,0.0002189107,0.00002743014,0.00006192284,0.004047905,0.000006325085,0.4359514,0.00006021253,0.0009334277,0.5571952],"study_design_scores_gemma":[0.0007718052,0.00002761197,0.001033036,0.0001689483,0.00001784251,0.0001155448,0.007193435,0.00003634557,0.9170337,0.00002568316,0.07298807,0.0005880191],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4694627,0.00006310816,5.112673e-7,0.00008975643,0.0000906122,0.000144355,0.00001839791,0.0002473355,0.5298833],"genre_scores_gemma":[0.9478348,0.00006641902,0.0001770193,0.000280552,0.0003721037,0.0001293958,0.0004214876,0.00008247606,0.0506357],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5566072,"threshold_uncertainty_score":0.9997583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01599630517810977,"score_gpt":0.2603681206064116,"score_spread":0.2443718154283018,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}