{"id":"W2045874157","doi":"10.1021/jo011093l","title":"Hydroformylation of Alkenes Employing Rhodium(I) Complexes and a Phosphine Oxide Ligand","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Hydroformylation; Rhodium; Chemistry; Ligand (biochemistry); Phosphine; Phosphine oxide; Enantioselective synthesis; Organic chemistry; Catalysis; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002925342,0.0001224874,0.000254612,0.00003467854,0.00008579664,0.00001659997,0.000243717,0.0000762352,0.002086788],"category_scores_gemma":[0.0001867443,0.00008795702,0.00008571961,0.0002664546,0.00008605532,0.00009895664,0.00005913215,0.0002021403,0.00000422419],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004569521,"about_ca_system_score_gemma":0.00002081703,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006752164,"about_ca_topic_score_gemma":0.000001070188,"domain_scores_codex":[0.9989835,0.000008986133,0.0004931785,0.00008008091,0.0003099318,0.0001243112],"domain_scores_gemma":[0.9988618,0.0001457748,0.0005855266,0.0001992461,0.0001291305,0.00007848693],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001911985,0.00005009374,0.001350171,0.00008818099,0.0001063738,0.000003220461,0.0004826277,0.00001473594,0.9960119,0.000001721471,0.0002699694,0.001601852],"study_design_scores_gemma":[0.0005749542,0.000009294758,0.0002178779,0.0000505309,0.0001487721,0.0003576839,0.0005296767,0.0004512614,0.9969619,0.00006889628,0.0005359985,0.00009318205],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941272,0.002770275,0.0001911752,0.0002954529,0.00001311394,0.00001519502,0.000004621501,0.00001194327,0.002571032],"genre_scores_gemma":[0.9981671,0.00076982,0.0001039651,0.00002836429,0.00009990762,3.010876e-7,0.000003245309,0.00001607227,0.0008112479],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004039885,"threshold_uncertainty_score":0.9988254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01297213084218223,"score_gpt":0.2111989230544853,"score_spread":0.198226792212303,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}