{"id":"W2046009375","doi":"10.1021/ma702049f","title":"One-Pot Synthesis of Hyperbranched Polyethylenes Tethered with Polymerizable Methacryloyl Groups via Selective Ethylene Copolymerization with Heterobifunctional Comonomers by Chain Walking Pd−Diimine Catalysis","year":2008,"lang":"en","type":"article","venue":"Macromolecules","topic":"Dendrimers and Hyperbranched Polymers","field":"Materials Science","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Copolymer; Diimine; Citation; Polymer science; Polymer chemistry; Computer science; Chemistry; Polymer; Materials science; World Wide Web; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002712468,0.0005677899,0.0009673528,0.0002963708,0.0004892795,0.00006011676,0.0004348565,0.0001879074,0.0004223482],"category_scores_gemma":[0.00004431308,0.0004948102,0.0001608168,0.0009169682,0.0008824728,0.0003871731,0.00008133989,0.0002072631,0.00002748204],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009900874,"about_ca_system_score_gemma":0.0001600116,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002449661,"about_ca_topic_score_gemma":0.0001919181,"domain_scores_codex":[0.9966496,0.0003163211,0.0006013865,0.0008935091,0.0007889063,0.0007503409],"domain_scores_gemma":[0.9982212,0.0002681726,0.0005360181,0.0005573053,0.0001861571,0.0002311348],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009519868,0.0003782053,0.001826861,0.00006738198,0.0004000121,0.0000277438,0.001360869,0.0001578982,0.9915075,0.0000480898,0.00004043099,0.003232991],"study_design_scores_gemma":[0.001195444,0.000544849,0.001335219,0.0001023589,0.0003054244,0.0001268954,0.0004974318,0.0001311392,0.9950211,0.00001744103,0.00006134455,0.0006613557],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9763662,0.002315655,0.01920423,0.0002394325,0.000143091,0.00037161,0.0001990071,0.0001565286,0.001004272],"genre_scores_gemma":[0.9946288,0.00007990822,0.004376717,0.0001664193,0.00006963683,0.0001492613,0.0001545811,0.0001307852,0.0002438942],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01826262,"threshold_uncertainty_score":0.9997504,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00845478993207448,"score_gpt":0.1945390275338992,"score_spread":0.1860842376018247,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}