{"id":"W2046049864","doi":"10.1021/la990598s","title":"Temperature-Dependence of the Electro-oxidation of the Irreversibly Chemisorbed As on Pt(111)","year":2001,"lang":"en","type":"article","venue":"Langmuir","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Overlayer; Chemistry; Enthalpy; Analytical Chemistry (journal); Cyclic voltammetry; Electrochemistry; Redox; Aqueous solution; Inorganic chemistry; Physical chemistry; Electrode; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001724122,0.0002688878,0.0003230436,0.0001323072,0.000112239,0.0003005565,0.0003351331,0.0003505133,0.001635518],"category_scores_gemma":[0.00041875,0.0001989155,0.0002012155,0.0002225999,0.0002650187,0.00021662,0.0001368885,0.0004678892,0.0002583656],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000249272,"about_ca_system_score_gemma":0.0001091127,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009836686,"about_ca_topic_score_gemma":0.001112926,"domain_scores_codex":[0.9998164,0.00002252608,0.00001495406,0.00004025869,0.00006230092,0.00004370198],"domain_scores_gemma":[0.9997857,0.00008224889,0.0000468347,0.00002086821,0.00004713896,0.00001715553],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002096839,0.00001816383,0.0003339089,0.00009337626,0.00001280734,0.00006166271,0.00006147446,0.0002101982,0.99801,0.0000560009,0.00004856088,0.0008842236],"study_design_scores_gemma":[0.000005286464,0.0001818949,0.003244191,0.000004744906,0.00001116744,0.00005199467,0.00003847928,0.001081611,0.9951113,0.00001957661,0.0002454986,0.000004242882],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982178,0.0002610031,0.0005049208,0.00003968311,0.00001377307,0.000009240402,0.0001980006,0.00003195781,0.0007235996],"genre_scores_gemma":[0.998337,0.000293041,0.0005815755,0.0000140174,0.000004814623,0.000009462124,0.0001704377,0.00001405184,0.0005755646],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001635518,"threshold_uncertainty_score":0.005471349,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004716161079878797,"score_gpt":0.2152281443107531,"score_spread":0.2105119832308743,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}