{"id":"W2046169172","doi":"10.1021/ic062212o","title":"Rational Design of a Covalently Tethered Dinuclear [Mn<sup>II</sup>(N<sub>3</sub>O<sub>2</sub>)Cl(OH<sub>2</sub>)]<sub>2</sub><sup>2+</sup> Macrocyclic Building Block:  Synthesis, Structure, and Magnetic Properties","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Ministerio de Economía y Competitividad","keywords":"Chemistry; Pentagonal bipyramidal molecular geometry; Crystallography; Covalent bond; Stoichiometry; Ligand (biochemistry); Antiferromagnetism; Molecule; Ion; Magnetic susceptibility; Schiff base; Stereochemistry; Crystal structure; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006433758,0.0003007677,0.0002540704,0.0000905355,0.000104368,0.000255175,0.0004822009,0.0002236052,0.0007511875],"category_scores_gemma":[0.0001383285,0.000156491,0.00008592466,0.000109767,0.0001409153,0.0001443141,0.0002307427,0.0002441695,0.0004281701],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004464524,"about_ca_system_score_gemma":0.0003270822,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008630444,"about_ca_topic_score_gemma":0.00252153,"domain_scores_codex":[0.9999421,0.000007655301,0.000005136886,0.00001837101,0.00001606719,0.00001064946],"domain_scores_gemma":[0.9999397,0.000004289829,0.00002229584,0.000005520281,0.000008342016,0.00001992329],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007508516,0.00003505508,0.0001654386,0.00006919504,0.000009558277,0.00004638917,0.00001775798,0.001389902,0.994112,0.0002870553,0.00006426657,0.003728209],"study_design_scores_gemma":[0.00007066036,0.0006244493,0.001319805,0.000008936195,0.00003034821,0.0001787844,0.00002404595,0.005211644,0.9821689,0.00007348762,0.01027521,0.00001376105],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9842413,0.0008087122,0.01159961,0.00008704855,0.0000243729,0.0001671999,0.0002222387,0.0002397354,0.002609704],"genre_scores_gemma":[0.9757632,0.0004487294,0.0208064,0.00006315303,0.000006261506,0.0001006247,0.0003820711,0.00004306633,0.002386412],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008630444,"threshold_uncertainty_score":0.003239274,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01298029743734451,"score_gpt":0.2113594983555086,"score_spread":0.1983792009181641,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}