{"id":"W2046169172","doi":"10.1021/ic062212o","title":"Rational Design of a Covalently Tethered Dinuclear [Mn<sup>II</sup>(N<sub>3</sub>O<sub>2</sub>)Cl(OH<sub>2</sub>)]<sub>2</sub><sup>2+</sup> Macrocyclic Building Block:  Synthesis, Structure, and Magnetic Properties","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Ministerio de Economía y Competitividad","keywords":"Chemistry; Pentagonal bipyramidal molecular geometry; Crystallography; Covalent bond; Stoichiometry; Ligand (biochemistry); Antiferromagnetism; Molecule; Ion; Magnetic susceptibility; Schiff base; Stereochemistry; Crystal structure; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.002127922,0.001889663,0.001845706,0.000513996,0.00135068,0.0007389102,0.002123279,0.001223329,0.0008348019],"category_scores_gemma":[0.002212968,0.002001947,0.000442205,0.001434175,0.001671448,0.0009662136,0.001438046,0.001307223,0.0001946074],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008063293,"about_ca_system_score_gemma":0.0008918554,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003853925,"about_ca_topic_score_gemma":0.00003387609,"domain_scores_codex":[0.9888079,0.0005960102,0.002878059,0.002791447,0.002543279,0.002383352],"domain_scores_gemma":[0.9932105,0.001514998,0.001416964,0.001970994,0.0009680825,0.0009184881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005587761,0.000446098,0.0002695591,0.001275496,0.0001725014,0.0001000341,0.001209004,0.002436588,0.9831768,0.00007327682,0.001775907,0.00850596],"study_design_scores_gemma":[0.002230328,0.0003366223,0.0009588075,0.0006968163,0.00038577,0.0008504927,0.0006414523,0.0043484,0.9861379,0.001015595,0.0003139506,0.002083923],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9928312,0.002068521,0.001066612,0.0004344189,0.000387264,0.001667632,0.0006910734,0.0006819788,0.0001713318],"genre_scores_gemma":[0.99504,0.0006048656,0.002249365,0.0002991793,0.00100451,0.0001962098,0.000111171,0.0004334066,0.00006127624],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006422037,"threshold_uncertainty_score":0.9999494,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01298029743734451,"score_gpt":0.2113594983555086,"score_spread":0.1983792009181641,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}