{"id":"W2046185967","doi":"10.1039/b412078g","title":"Quantitative determination of hexamethylene diisocyanate (HDI), 2,4-toluene diisocyanate (2,4-TDI) and 2,6-toluene diisocyanate (2,6-TDI) monomers at ppt levels in air by alkaline adduct coordination ionspray tandem mass spectrometry","year":2005,"lang":"en","type":"article","venue":"Journal of Environmental Monitoring","topic":"Occupational exposure and asthma","field":"Medicine","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut de Recherche Robert-Sauvé en Santé et en Sécurité du Travail; Université du Québec à Montréal","funders":"","keywords":"Toluene diisocyanate; Hexamethylene diisocyanate; Toluene; Chemistry; Monomer; Adduct; Polymer chemistry; Polyurethane; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006415243,0.0007267902,0.0004438626,0.0006403197,0.0002239288,0.0006098828,0.0005603384,0.0007014053,0.0008301265],"category_scores_gemma":[0.0009110781,0.0003067828,0.0002599187,0.0003997236,0.0004776977,0.0003977208,0.0005226411,0.00053518,0.00048812],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004617255,"about_ca_system_score_gemma":0.0005701029,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008978799,"about_ca_topic_score_gemma":0.001654227,"domain_scores_codex":[0.9987367,0.0001417883,0.00004523714,0.0003566407,0.0006477942,0.00007183209],"domain_scores_gemma":[0.9994501,0.0001301298,0.0001043336,0.00004057328,0.0002228644,0.0000518314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003074811,0.00002489481,0.001228218,0.00002992036,0.00001052342,0.00002030516,0.00002084861,0.00007247479,0.994003,0.00003668255,0.0000267066,0.004495603],"study_design_scores_gemma":[0.000005390294,0.0001962683,0.007898379,0.000005474119,0.00001902421,0.0001697803,0.00003442152,0.001814383,0.9890137,0.00004293034,0.0007911565,0.000008958657],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.908707,0.004396026,0.08281025,0.0001177263,0.00006779922,0.0001988381,0.0006379387,0.0005009001,0.002563464],"genre_scores_gemma":[0.9118073,0.004915026,0.07508129,0.0001968319,0.00008564785,0.0003479878,0.0009623313,0.00008711766,0.006516472],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008978799,"threshold_uncertainty_score":0.003392756,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01617269808351835,"score_gpt":0.2807620596842599,"score_spread":0.2645893616007415,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}