{"id":"W2046186705","doi":"10.1002/hlca.200790210","title":"Reactions of Dimethoxycarbene with <i>N</i>‐Tosylated Imines","year":2007,"lang":"en","type":"article","venue":"Helvetica Chimica Acta","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Adduct; Decomposition; Thermal decomposition; Stereochemistry; Xanthone; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001949521,0.0004964666,0.0002166874,0.0001640102,0.0001577932,0.000164728,0.0003336298,0.0003720754,0.001501491],"category_scores_gemma":[0.0002921386,0.0001732817,0.000249653,0.0001573497,0.0001771984,0.0002832021,0.0002343616,0.0004234792,0.0003514961],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002770358,"about_ca_system_score_gemma":0.0001436816,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003550534,"about_ca_topic_score_gemma":0.0007552101,"domain_scores_codex":[0.9998055,0.0000455977,0.00001007126,0.00004309428,0.00003429258,0.00006132671],"domain_scores_gemma":[0.9998494,0.00002836463,0.00004306282,0.0000253734,0.0000173202,0.00003653474],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001102033,0.00002173413,0.0001100036,0.00006651451,0.00001179712,0.0001283805,0.00006272161,0.0001493779,0.9977054,0.0002835716,0.0000708439,0.001279418],"study_design_scores_gemma":[0.000007427142,0.0001378191,0.0003418234,0.00000284918,0.000004590726,0.0000894129,0.000007878979,0.0001723114,0.9979965,0.0000241631,0.001211469,0.000003710358],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895229,0.0009551082,0.003297439,0.00005426741,0.0000413928,0.00004792637,0.000187162,0.0000696436,0.005824226],"genre_scores_gemma":[0.9952812,0.000363462,0.001600918,0.00002574249,0.000007823975,0.00002276977,0.0001740758,0.00001908597,0.002504962],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001501491,"threshold_uncertainty_score":0.005023003,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008112726153261805,"score_gpt":0.2345389250432235,"score_spread":0.2264261988899617,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}