{"id":"W2046434307","doi":"10.1039/b515751j","title":"Mechanism of action of sensors for reactive oxygen species based on fluorescein–phenol coupling: the case of 2-[6-(4′-hydroxy)phenoxy-3H-xanthen-3-on-9-yl]benzoic acid","year":2006,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Wilfrid Laurier University","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario; Advanced Foods and Materials Network","keywords":"Chemistry; Radical; Flash photolysis; Photochemistry; Potassium ferricyanide; Benzoic acid; Phenol; Oxidizing agent; Alkoxy group; Electron paramagnetic resonance; Homolysis; Hydrolysis; Reaction rate constant; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002351132,0.0003678347,0.0004332541,0.00005214808,0.0001379074,0.000009620547,0.0003198527,0.000279286,0.00003542969],"category_scores_gemma":[0.0002005167,0.0003101975,0.0002998943,0.0002530247,0.0003104226,0.000004141069,0.00008693287,0.0001550525,0.00000143072],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006775309,"about_ca_system_score_gemma":0.0001648586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000424451,"about_ca_topic_score_gemma":0.00001770267,"domain_scores_codex":[0.9982338,0.00003749802,0.0005058824,0.0005581239,0.0002864963,0.0003782285],"domain_scores_gemma":[0.9981914,0.00006267674,0.0005335137,0.0008401193,0.0003220028,0.00005032886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003652127,0.0002806571,0.0000245776,0.0002366747,0.0001919351,0.00002651382,0.00003888254,0.00007286818,0.9982064,0.0002145879,0.0002583499,0.00008339192],"study_design_scores_gemma":[0.001014396,0.00056809,0.00005010921,0.00007258869,0.000125232,0.00005500382,0.0003877043,0.0006682284,0.9961626,0.0001924201,0.0004263062,0.0002772983],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9781823,0.0007269213,0.01899112,0.0001917485,0.0000736888,0.0005501247,0.0002145191,0.00002080263,0.001048765],"genre_scores_gemma":[0.998886,0.00007258202,0.0003593795,0.00004676784,0.0001293459,0.0000416909,0.0001497563,0.00007267868,0.0002417465],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02070374,"threshold_uncertainty_score":0.999935,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009309339482853339,"score_gpt":0.2409046609852614,"score_spread":0.2315953215024081,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}