{"id":"W2046434307","doi":"10.1039/b515751j","title":"Mechanism of action of sensors for reactive oxygen species based on fluorescein–phenol coupling: the case of 2-[6-(4′-hydroxy)phenoxy-3H-xanthen-3-on-9-yl]benzoic acid","year":2006,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Electron Spin Resonance Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Wilfrid Laurier University","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario; Advanced Foods and Materials Network","keywords":"Chemistry; Radical; Flash photolysis; Photochemistry; Potassium ferricyanide; Benzoic acid; Phenol; Oxidizing agent; Alkoxy group; Electron paramagnetic resonance; Homolysis; Hydrolysis; Reaction rate constant; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004600438,0.0005649355,0.0003706298,0.0001749824,0.0001570478,0.0003189374,0.0005829334,0.0009202251,0.0007042308],"category_scores_gemma":[0.0003516437,0.0002579162,0.0003483602,0.00007098209,0.0005415252,0.0005843652,0.0002028753,0.0004897404,0.000327401],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002792628,"about_ca_system_score_gemma":0.000162071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000204582,"about_ca_topic_score_gemma":0.000145429,"domain_scores_codex":[0.9998074,0.0000382395,0.000006874776,0.00005347179,0.00004408831,0.00004989736],"domain_scores_gemma":[0.9998067,0.00006134258,0.00006687216,0.00001443532,0.00001989414,0.00003075197],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006788223,0.00002091106,0.0001032235,0.00005062077,0.000007355539,0.0001047084,0.00002635974,0.00007665416,0.9981974,0.0002956946,0.00002546892,0.001023852],"study_design_scores_gemma":[0.000008700565,0.0001386628,0.0002097162,0.000001550977,0.000007146645,0.0001191973,0.000004352583,0.000494791,0.9986457,0.00003458502,0.0003317656,0.000003775147],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9535657,0.00190171,0.04193513,0.0004134098,0.0001040892,0.0001342168,0.00008710228,0.000323653,0.001534955],"genre_scores_gemma":[0.9874264,0.0005899378,0.01040014,0.0001235052,0.00001682647,0.00005487799,0.00005656388,0.00001178388,0.001319965],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009202251,"threshold_uncertainty_score":0.002432942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009309339482853339,"score_gpt":0.2409046609852614,"score_spread":0.2315953215024081,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}