{"id":"W2046461642","doi":"10.1021/jo052045u","title":"Synthesis of a Nonavalent Mannoside Glycodendrimer Based on Pentaerythritol","year":2006,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Pentaerythritol; Chemistry; Dendrimer; Propargyl; Sonogashira coupling; Ether; Convergent synthesis; Polymer chemistry; Organic chemistry; Palladium; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007770258,0.0003445185,0.0002663491,0.000127794,0.0001081183,0.0002352486,0.0001709326,0.0002400665,0.0007006213],"category_scores_gemma":[0.0001031396,0.0001039394,0.0002019399,0.0001504216,0.0001107582,0.0002065321,0.0002105183,0.0003828353,0.0005207607],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002034976,"about_ca_system_score_gemma":0.0002044722,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002912212,"about_ca_topic_score_gemma":0.0005488289,"domain_scores_codex":[0.999933,0.000006942584,0.000005819075,0.00001633747,0.00002210523,0.00001578735],"domain_scores_gemma":[0.9999294,0.000007190412,0.00001933013,0.00001302798,0.000009854181,0.00002112314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001943304,0.000005241443,0.00002919951,0.00001504967,0.000003087892,0.00006152945,0.000004765448,0.0001311387,0.9979535,0.0001273146,0.0000131391,0.001636546],"study_design_scores_gemma":[0.000008662499,0.0001758924,0.0007774316,0.000003188032,0.0000136201,0.000217396,0.000004716762,0.0005310684,0.995583,0.00003828812,0.002641719,0.000005018836],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9763743,0.001158413,0.01583354,0.00007778234,0.00005714519,0.00008004747,0.0002623229,0.0001655433,0.00599091],"genre_scores_gemma":[0.9656086,0.001341695,0.02522789,0.00005536568,0.00001504878,0.00003473337,0.0005143111,0.00007777209,0.007124559],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007006213,"threshold_uncertainty_score":0.002343833,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006659291069397741,"score_gpt":0.1999204395675308,"score_spread":0.193261148498133,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}