{"id":"W2046511098","doi":"10.1139/v05-119","title":"Kinetics of glycoluril template-directed Claisen condensations Effect of thionation of the glycoluril","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Deprotonation; Medicinal chemistry; Alkyl; Protonation; Kinetics; Stereochemistry; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001807017,0.0001548718,0.000374559,0.00006072669,0.00003975627,0.00001006562,0.0004513244,0.0002433687,0.001893951],"category_scores_gemma":[0.001078771,0.0001325322,0.0002416185,0.0002388026,0.0001850819,0.00007580618,0.00002346087,0.0003665119,0.000001511342],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002998691,"about_ca_system_score_gemma":0.0005857221,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003172905,"about_ca_topic_score_gemma":0.0005822121,"domain_scores_codex":[0.9984602,0.00002471053,0.000790911,0.0001198425,0.0004084094,0.0001959011],"domain_scores_gemma":[0.9974335,0.0003043443,0.001051912,0.0003589447,0.0005546885,0.0002966154],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005108031,0.00003064584,0.0006447266,0.0002904156,0.00007456956,0.000003845702,0.0001010785,0.0002491376,0.9967203,0.00001551035,0.001215619,0.0006030559],"study_design_scores_gemma":[0.0008587354,0.00002951763,0.0002522333,0.0002695021,0.00009435383,0.0001123039,0.00007382818,0.00007822429,0.9938068,0.00009712372,0.00422563,0.0001016955],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990886,0.0001871726,0.00001970309,0.0002816723,0.0001017178,0.00005883489,0.0001550098,0.000008210925,0.008301618],"genre_scores_gemma":[0.9988729,0.000009244041,0.0002485457,0.00001686035,0.0001731892,0.000002102497,0.0000184546,0.00002077076,0.0006378794],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007986893,"threshold_uncertainty_score":0.9990184,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006291574337577445,"score_gpt":0.2117400743256486,"score_spread":0.2054484999880712,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}