{"id":"W2046581542","doi":"10.1021/ol0494616","title":"Photochemical Deuterium Exchange of the <i>m</i>-Methyl Group of 3-Methylbenzophenone and 3-Methylacetophenone in Acidic D<sub>2</sub>O","year":2004,"lang":"en","type":"article","venue":"Organic Letters","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Deuterium; Photochemistry; Group (periodic table); Methyl group; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008536922,0.0003904527,0.000134281,0.00007744817,0.0002130451,0.0001717097,0.0002325085,0.0001773965,0.001832242],"category_scores_gemma":[0.0001795293,0.0001069609,0.00007625779,0.0001793969,0.0003512164,0.0001931415,0.0001460031,0.0002968792,0.0002741437],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003491814,"about_ca_system_score_gemma":0.0001769828,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001894541,"about_ca_topic_score_gemma":0.002501854,"domain_scores_codex":[0.9999397,0.000009736346,0.000001643107,0.0000160481,0.00001106403,0.00002175669],"domain_scores_gemma":[0.9999082,0.00003889057,0.00002613401,0.000007684608,0.000006464464,0.0000126223],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000173067,0.000006327202,0.0001519102,0.00006490786,0.000004072317,0.00006504903,0.00002920358,0.0001317667,0.9976456,0.0001094093,0.00007985982,0.001538982],"study_design_scores_gemma":[0.000006849505,0.00006423953,0.0006667403,0.00000175643,0.000003377403,0.00008700763,0.00001243137,0.0001505508,0.9983367,0.00002328235,0.0006449539,0.000002122815],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894475,0.001759548,0.003094774,0.0000886769,0.00004363217,0.00002611491,0.0002382675,0.00006186019,0.005239645],"genre_scores_gemma":[0.9967444,0.0005469646,0.0008072939,0.00002769002,0.000005703069,0.000008632813,0.0001426669,0.00001007853,0.001706562],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001894541,"threshold_uncertainty_score":0.006129503,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005886567265621163,"score_gpt":0.1935841787217115,"score_spread":0.1876976114560904,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}