{"id":"W2046628854","doi":"10.1039/b506706e","title":"Ketonization of the remarkably strongly acidic elongated enol generated by flash photolytic decarboxylation of p-benzoylphenylacetic acid in aqueous solution","year":2005,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria; University of Toronto","funders":"","keywords":"Enol; Decarboxylation; Chemistry; Aqueous solution; Photochemistry; Flash (photography); Oxygen; Acid strength; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001057665,0.0002783391,0.0001167863,0.0001242562,0.0001321978,0.0001687864,0.0001496949,0.0001894441,0.002170203],"category_scores_gemma":[0.000109425,0.00009111934,0.0001064638,0.0001306837,0.0001762719,0.0002739854,0.0001354571,0.0004177456,0.0004732526],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001902442,"about_ca_system_score_gemma":0.0001801735,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005744425,"about_ca_topic_score_gemma":0.0009071935,"domain_scores_codex":[0.9999442,0.000006926657,0.000002615124,0.00001157698,0.000009467419,0.00002523191],"domain_scores_gemma":[0.9999254,0.00001261853,0.00001620177,0.000007269357,0.00001355358,0.00002490777],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001384976,0.000008065619,0.00008767793,0.00003198422,0.000003072859,0.0000796165,0.00002193713,0.00006973868,0.9977162,0.0002367623,0.00003303058,0.001573521],"study_design_scores_gemma":[0.000006074602,0.00009957893,0.0005285111,0.000001847816,0.000002949351,0.00005357202,0.00002013333,0.00009792959,0.997721,0.00003082338,0.001434649,0.000002842586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883252,0.0008699596,0.005780332,0.00007924317,0.00005126072,0.0000222046,0.0001609254,0.00004412718,0.004666677],"genre_scores_gemma":[0.9944536,0.000449948,0.001609788,0.00002799565,0.000005306825,0.000006110157,0.0001560591,0.00001467418,0.003276382],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002170203,"threshold_uncertainty_score":0.007260084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01333420425842874,"score_gpt":0.2463209001997373,"score_spread":0.2329866959413086,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}