{"id":"W2046814017","doi":"10.1139/v00-131","title":"Synthesis, characterization, and CN bond cleavage of tungsten(VI)arylimido-calix[4]arene complexes","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Alberta","keywords":"Chemistry; Calixarene; Denticity; Bond cleavage; Stereochemistry; Cleavage (geology); Yield (engineering); Tungsten; Medicinal chemistry; Crystallography; Crystal structure; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002135356,0.0002525202,0.0001999622,0.0001612963,0.0001154599,0.0003236996,0.0002937367,0.0002867909,0.0007858045],"category_scores_gemma":[0.0004861038,0.0001243958,0.0001108368,0.0001505117,0.0001730817,0.0001890192,0.0001134366,0.000268956,0.0001845196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002701666,"about_ca_system_score_gemma":0.0001626159,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00108508,"about_ca_topic_score_gemma":0.001498586,"domain_scores_codex":[0.9998318,0.00001750232,0.00001252466,0.00003532506,0.00007990684,0.00002296963],"domain_scores_gemma":[0.999791,0.0000296752,0.00006028351,0.00002973906,0.00005915367,0.00003026881],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003204401,0.000009282322,0.0001573111,0.00001884954,0.000002211646,0.00002216649,0.00001566696,0.00009944058,0.9987665,0.00004514854,0.00001200778,0.0008192535],"study_design_scores_gemma":[0.000004959805,0.00009161724,0.001308392,0.00000194685,0.000004269499,0.00006575009,0.00001028796,0.0005280289,0.9970439,0.00001113792,0.0009260681,0.000003648951],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993709,0.0003864192,0.003793751,0.00002491052,0.000005617569,0.00008761207,0.0002945495,0.0000380105,0.001660191],"genre_scores_gemma":[0.9900002,0.0004018144,0.006656242,0.00001780508,0.000003684788,0.00005642464,0.0007395771,0.0000231349,0.002101235],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00108508,"threshold_uncertainty_score":0.002628744,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01150419123156403,"score_gpt":0.1979986488203455,"score_spread":0.1864944575887814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}