{"id":"W2046817480","doi":"10.1055/s-1972-21927","title":"Dethioacetalization via S-Methylation","year":2002,"lang":"en","type":"article","venue":"Synthesis","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Manitoba","funders":"","keywords":"Chemistry; Methylation; Biochemistry; Gene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005912817,0.0001024927,0.0001191451,0.0000333262,0.0001123344,0.00002482166,0.0000930316,0.0001351387,0.0217342],"category_scores_gemma":[0.00032037,0.0000913811,0.0000953187,0.0001123167,0.00003619288,0.00008706308,0.00001694758,0.00008515565,0.000511577],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005529481,"about_ca_system_score_gemma":0.000002560047,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002554146,"about_ca_topic_score_gemma":0.000004317132,"domain_scores_codex":[0.999315,0.00001361379,0.0001680138,0.0001888251,0.0001588507,0.0001556625],"domain_scores_gemma":[0.9993289,0.0002862576,0.00006615249,0.0002264848,0.00002767336,0.00006456133],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000002349997,0.00009184821,0.0004244391,0.00002972572,0.00002744937,0.000001137456,0.00006200159,0.00001020925,0.8169646,0.0001485978,0.0009157627,0.1813219],"study_design_scores_gemma":[0.00005261831,0.000001348728,0.0001285688,0.00002791404,0.00004439849,0.000006658691,0.00002900933,0.004402513,0.9599487,0.0003732865,0.03483137,0.0001536561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3389664,0.0007575887,0.006428194,0.002250923,0.0002067264,0.00009559222,0.00002344072,0.0006317482,0.6506394],"genre_scores_gemma":[0.9966649,0.00009465,0.0004263335,0.00003284365,0.0001687782,0.00003106764,0.000004580961,0.00002061877,0.002556253],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6576985,"threshold_uncertainty_score":0.9791601,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01901302999290409,"score_gpt":0.2138820514268027,"score_spread":0.1948690214338986,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}