{"id":"W2047071108","doi":"10.1055/s-2006-949420","title":"Synthesis of Annulated N-Containing Heterocycles via C-H Activation","year":2006,"lang":"en","type":"article","venue":"Synfacts","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Norbornene; Aryl; Alkylation; Palladium; Catalysis; Combinatorial chemistry; Organic chemistry; Stereochemistry; Medicinal chemistry; Alkyl; Polymer; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001383057,0.0001176926,0.000179075,0.00007763146,0.0000531393,0.00001606509,0.00008924702,0.0001045845,0.001282632],"category_scores_gemma":[0.0003532278,0.0001242664,0.00006732453,0.0001470694,0.0000378699,0.0001370008,0.00002745453,0.00007013116,0.00002117189],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007724797,"about_ca_system_score_gemma":0.00003047989,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000341683,"about_ca_topic_score_gemma":0.00001041646,"domain_scores_codex":[0.9990976,0.00002327806,0.0003064735,0.0001953059,0.0002277116,0.0001496135],"domain_scores_gemma":[0.9990532,0.0003739526,0.0001984998,0.0002361068,0.0001024652,0.00003577383],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006527658,0.00006635388,0.008113662,0.00009928032,0.00004178268,0.0000019125,0.0000514391,0.001500886,0.9771346,0.0003547654,0.000298454,0.01227157],"study_design_scores_gemma":[0.0002032677,0.000005714297,0.01286417,0.0000716266,0.00002495298,0.00000691273,0.0000452983,0.001168318,0.9825376,0.0008862115,0.002055265,0.0001306188],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9603781,0.00002543464,0.01681218,0.00008072313,0.00007366466,0.00004818591,0.00001665858,0.0001247417,0.02244029],"genre_scores_gemma":[0.9974068,0.00000127075,0.001629395,0.00002326017,0.0001079654,0.00001108002,0.00009057421,0.0000225829,0.0007071189],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03702863,"threshold_uncertainty_score":0.9996303,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01659571135936188,"score_gpt":0.2627966342068003,"score_spread":0.2462009228474384,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}