{"id":"W2047072586","doi":"10.1021/ic100914x","title":"Monomeric and Dimeric Nickel Complexes Derived from a Pincer Ligand Featuring a Secondary Amine Donor Moiety","year":2010,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":61,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Deprotonation; Moiety; Dimer; Pincer ligand; Ligand (biochemistry); Amine gas treating; Adduct; Medicinal chemistry; Nickel; Stereochemistry; Bromide; Monomer; Benzyl bromide; Pincer movement; Crystallography; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0000764207,0.0004631385,0.0006019344,0.00003224452,0.0002193804,0.0001595993,0.0005209869,0.0002760495,0.03853012],"category_scores_gemma":[0.0001152463,0.0004693732,0.0001639618,0.0002844451,0.0002690459,0.0001496034,0.000442954,0.000749939,0.000060956],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006922781,"about_ca_system_score_gemma":0.0001196012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003351378,"about_ca_topic_score_gemma":0.00006180578,"domain_scores_codex":[0.998008,0.000008673843,0.0004567057,0.000827779,0.0002403775,0.0004585203],"domain_scores_gemma":[0.9982792,0.0001885043,0.0002338949,0.0009402674,0.00006436382,0.0002937807],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002041366,0.0001030303,0.004554291,0.0001555498,0.000230496,0.000010353,0.0002188992,2.301483e-7,0.9850172,0.000002032838,0.0001271603,0.009560317],"study_design_scores_gemma":[0.000749626,0.000005409338,0.0154575,0.0000339559,0.000168546,0.00006863922,0.0003452667,0.00007289211,0.970206,0.0000972113,0.01220609,0.0005889374],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9904511,0.001455795,0.00001509911,0.000199532,0.00009991151,0.0000594215,0.0001548744,0.0001824077,0.007381876],"genre_scores_gemma":[0.9944233,0.000136028,0.0005846309,0.00006837575,0.0005730155,0.00002911476,0.0002231755,0.00008223415,0.003880118],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03846916,"threshold_uncertainty_score":0.9997758,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006573946377044184,"score_gpt":0.1957179020313889,"score_spread":0.1891439556543447,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}