{"id":"W2047097862","doi":"10.1021/ac201070j","title":"Online Comprehensive Two-Dimensional Characterization of Puff-by-Puff Resolved Cigarette Smoke by Hyphenation of Fast Gas Chromatography to Single-Photon Ionization Time-of-Flight Mass Spectrometry: Quantification of Hazardous Volatile Organic Compounds","year":2011,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Mass spectrometry; Gas chromatography; Smoke; Acrolein; Analytical Chemistry (journal); Time-of-flight mass spectrometry; DART ion source; Benzene; Electron ionization; Photoionization; Ionization; Chromatography; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003014892,0.0007622133,0.0003475031,0.0007428019,0.0002969506,0.0004019639,0.0004284771,0.000476369,0.001248055],"category_scores_gemma":[0.0004831345,0.0002612775,0.0003007941,0.0002894025,0.0003043427,0.0004615324,0.0006224657,0.0005880962,0.0005014316],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002146312,"about_ca_system_score_gemma":0.0005380197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008574111,"about_ca_topic_score_gemma":0.002295283,"domain_scores_codex":[0.9996608,0.00002655433,0.00001170743,0.0001150232,0.0001566645,0.00002917207],"domain_scores_gemma":[0.9998357,0.00004564855,0.00002425068,0.00002432573,0.00005441955,0.00001562576],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004109919,0.00002430758,0.001883262,0.00004236546,0.00001187782,0.00005516389,0.00004602662,0.00006788672,0.9864753,0.0001161177,0.00006986449,0.01116685],"study_design_scores_gemma":[0.000005095936,0.0001208992,0.01714729,0.0000106915,0.00002361815,0.0004752559,0.00006739102,0.005322707,0.9737925,0.0001967978,0.002810305,0.00002745995],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8378389,0.002058848,0.1536314,0.0001433006,0.0000815381,0.0002077166,0.001787641,0.00106589,0.003184701],"genre_scores_gemma":[0.828626,0.002569511,0.1592461,0.0003067187,0.00004127057,0.0004219834,0.001863098,0.0002396597,0.006685594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001248055,"threshold_uncertainty_score":0.004175186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0171295821705842,"score_gpt":0.2269264190658342,"score_spread":0.20979683689525,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}