{"id":"W2047160019","doi":"10.1139/v02-058","title":"A facile methodology for the synthesis and detection of N7-guanine adduct of sulfur mustard as a biomarker","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Pesticide Exposure and Toxicity","field":"Agricultural and Biological Sciences","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Adduct; Guanine; Sulfur mustard; In vivo; Biomarker; Sulfur; In vitro; High-performance liquid chromatography; Chromatography; Organic chemistry; Biochemistry; Nucleotide; Gene; Toxicity","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003198104,0.00005865657,0.0001667192,0.00000974649,0.00006167679,0.000007821196,0.0001235572,0.00007074355,0.000721001],"category_scores_gemma":[0.0009619265,0.00002241149,0.00008439107,0.00009293888,0.0001117775,0.0000296206,0.000005662509,0.00006662931,2.983386e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001495516,"about_ca_system_score_gemma":0.00003068613,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001717309,"about_ca_topic_score_gemma":0.003651467,"domain_scores_codex":[0.999513,0.00003534344,0.0002074617,0.0000644355,0.00006060905,0.0001191817],"domain_scores_gemma":[0.9988061,0.0007234247,0.0001911009,0.00002701455,0.0001139022,0.000138477],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002124004,0.000006066966,0.0003851124,0.00001547681,0.00003416149,0.000005421469,0.00006051695,8.569232e-7,0.953276,0.000001616787,0.0002877775,0.04590571],"study_design_scores_gemma":[0.00008811147,0.0001158911,0.009628976,0.00002394114,0.00004496768,0.0002500538,0.0003565868,0.00002841136,0.9850676,0.0001660937,0.004175978,0.00005335586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976678,0.001141563,0.00003431121,0.0007002694,0.00003342886,0.0000397919,0.00006517008,0.000001170717,0.0003164167],"genre_scores_gemma":[0.9996545,0.00003144669,0.00009849016,0.00003105602,0.00008740981,0.000001968637,4.874199e-7,5.452202e-7,0.00009413576],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04585236,"threshold_uncertainty_score":0.7894455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06605655441696824,"score_gpt":0.2364803585594859,"score_spread":0.1704238041425177,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}