{"id":"W2047331343","doi":"10.1021/jp804193u","title":"Chemical Stability and Reactivity of Deprotonated Oligonucleotides (DNA) in the Gas Phase: Protonation and Solvation with Hydrogen Bromide","year":2008,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Solvation; Deprotonation; Protonation; Reactivity (psychology); Gas phase; Oligonucleotide; Chemistry; Hydrogen; Bromide; Phase (matter); DNA; Photochemistry; Solvent; Inorganic chemistry; Physical chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002965287,0.000266248,0.0001652941,0.00009036704,0.0001218647,0.0002082638,0.0002299373,0.0003365366,0.0007760985],"category_scores_gemma":[0.0003827903,0.0001533166,0.0001265473,0.0001028471,0.0003280497,0.0001815687,0.0001244447,0.0002342086,0.0001774557],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002459405,"about_ca_system_score_gemma":0.0001293169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008084888,"about_ca_topic_score_gemma":0.0007221558,"domain_scores_codex":[0.9998166,0.00004182444,0.00001107777,0.00004809953,0.00005234576,0.00003011002],"domain_scores_gemma":[0.9997883,0.00006604271,0.00005415264,0.00001507213,0.00003924145,0.00003724118],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000069743,0.000002477728,0.0001138223,0.00001117831,0.000003737318,0.00001461348,0.00002037845,0.00006793789,0.9994152,0.0000188389,0.000005770805,0.0002564274],"study_design_scores_gemma":[0.00000757109,0.0001475185,0.001586357,0.000001844184,0.000005790745,0.00007089752,0.00002073022,0.0003686605,0.9974517,0.00001563281,0.000318782,0.000004383859],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980808,0.0003405344,0.001120717,0.00002662334,0.000006163095,0.000004568119,0.0001194002,0.00001720362,0.0002838764],"genre_scores_gemma":[0.9966269,0.0003359656,0.001691836,0.00002611884,0.000005186434,0.00001120209,0.0003494934,0.00001871533,0.0009346816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008084888,"threshold_uncertainty_score":0.002596378,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01033235311679855,"score_gpt":0.2390049858414004,"score_spread":0.2286726327246018,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}