{"id":"W2047569296","doi":"10.1002/chin.201405169","title":"ChemInform Abstract: Stereodivergent Access to cis‐ and trans‐3,5‐Disubstituted 1,4‐Thiazane 1‐Oxides by Cyclization of Homochiral β‐Amino Sulfoxides and Sulfones. The Preparation of Isomeric Ant Venom Alkaloids.","year":2014,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Base (topology); Stereochemistry; ANT; Medicinal chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009580878,0.0004846109,0.00009181125,0.0003109797,0.0002210814,0.0001860701,0.0002363823,0.000237699,0.01366309],"category_scores_gemma":[0.00007968957,0.0001792758,0.00009752988,0.0001874942,0.0001912139,0.0003062784,0.0002510786,0.0004720741,0.002966585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003538373,"about_ca_system_score_gemma":0.0004224024,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005687727,"about_ca_topic_score_gemma":0.001409735,"domain_scores_codex":[0.9999466,0.00000453057,0.000002183317,0.00001167145,0.00001885715,0.00001619044],"domain_scores_gemma":[0.9999712,0.00000356596,0.000007334383,0.000003351239,0.000006518397,0.000008035294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000453748,0.00009296725,0.0002821701,0.0003430038,0.00002170358,0.0003329502,0.0001469246,0.0005351957,0.9460129,0.008467934,0.006512897,0.03679766],"study_design_scores_gemma":[0.00006313364,0.0003714231,0.0009272884,0.00001813537,0.00001947888,0.0004589936,0.00003848704,0.0006994015,0.9527245,0.0005012637,0.04416253,0.00001529387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.642734,0.006657481,0.03189668,0.001416771,0.000506804,0.0002172506,0.003972065,0.001825328,0.3107736],"genre_scores_gemma":[0.9514102,0.00414471,0.005122565,0.0001933225,0.00007471264,0.00005600278,0.001841513,0.0001140632,0.037043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01366309,"threshold_uncertainty_score":0.04570758,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0150293774331597,"score_gpt":0.2546029859762641,"score_spread":0.2395736085431044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}