{"id":"W2047627775","doi":"10.1039/c1dt10342c","title":"PNP pincer osmium polyhydrides for catalytic dehydrogenation of primary alcohols","year":2011,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":94,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Wilfrid Laurier University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pincer movement; Dehydrogenation; Catalysis; Chemistry; Osmium; Combinatorial chemistry; Primary (astronomy); Photochemistry; Organic chemistry; Ruthenium; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009924401,0.0003123629,0.0002335677,0.0001397285,0.0001115386,0.0001905955,0.0002998709,0.0001701652,0.0006602716],"category_scores_gemma":[0.0001580493,0.0001190245,0.0001604714,0.0001411699,0.0001810038,0.0002836112,0.000388879,0.0002724807,0.0002470036],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002347841,"about_ca_system_score_gemma":0.000138294,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000349974,"about_ca_topic_score_gemma":0.0007460047,"domain_scores_codex":[0.9998956,0.00001191838,0.000007171774,0.00001784094,0.00004401191,0.00002354056],"domain_scores_gemma":[0.9999534,0.000007147007,0.00001469683,0.000004907894,0.000008889498,0.00001092619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000155877,0.00001441601,0.0001729072,0.0002090482,0.0000134151,0.00007764366,0.0000522433,0.0004658971,0.9899649,0.0006729478,0.0001336332,0.008067087],"study_design_scores_gemma":[0.000008668656,0.000113854,0.0002767368,0.000003401889,0.000007651878,0.0001095801,0.000009196469,0.000536298,0.9959393,0.00003992376,0.002951367,0.000004189323],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9758992,0.002880285,0.01357237,0.00009856179,0.00005402734,0.00009057183,0.000139388,0.000212263,0.007053314],"genre_scores_gemma":[0.9928539,0.001049879,0.004061401,0.00002808652,0.000007823607,0.00002818069,0.0001103503,0.00003515743,0.001825132],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006602716,"threshold_uncertainty_score":0.002208829,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03340501707089179,"score_gpt":0.2477522946470221,"score_spread":0.2143472775761303,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}