{"id":"W2047736756","doi":"10.1021/ac9913098","title":"A Bulk Electrolysis Raman Spectroelectrochemical Cell Using a Rotating Electrode","year":2000,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Raman spectroscopy; Electrolysis; Electrode; Bulk electrolysis; Platinum; Electrolytic cell; Analytical Chemistry (journal); Rotation (mathematics); Optics; Chromatography; Physical chemistry; Catalysis; Electrolyte; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009761457,0.001059149,0.001504208,0.0010546,0.0009811284,0.0008558714,0.002746342,0.001363487,0.005889505],"category_scores_gemma":[0.0006791768,0.001122778,0.0005108835,0.0007175944,0.0003738696,0.001063425,0.001173997,0.001917189,0.005840963],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004333493,"about_ca_system_score_gemma":0.00106942,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006807561,"about_ca_topic_score_gemma":0.001236575,"domain_scores_codex":[0.9982594,0.000109598,0.000115842,0.0004899026,0.0009278919,0.00009747738],"domain_scores_gemma":[0.9989797,0.0002338988,0.00006954394,0.0002240876,0.0003870473,0.0001056823],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006851878,0.00004964997,0.0001335492,0.0001667068,0.00001103667,0.00006145218,0.0000166325,0.0001249583,0.977413,0.000446801,0.001266861,0.02024076],"study_design_scores_gemma":[0.0001051434,0.0007054199,0.001613557,0.00002687219,0.00006300964,0.001706351,0.00003367559,0.008499697,0.9397154,0.0007405138,0.04669009,0.0001003036],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.1276976,0.00395365,0.8409949,0.0005184098,0.001091702,0.002025545,0.004616472,0.01051785,0.008583755],"genre_scores_gemma":[0.1313567,0.002518173,0.8415455,0.0005290724,0.0004100623,0.002145236,0.003564303,0.0006304787,0.01730047],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.005889505,"threshold_uncertainty_score":0.01970237,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006965976831350263,"score_gpt":0.2340823570344226,"score_spread":0.2271163802030723,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}