{"id":"W2047775361","doi":"10.1562/0031-8655(2002)0750362tlirot2.0.co2","title":"The Light-induced Reactions of Tryptophan with Halocompounds¶","year":2002,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Indole test; Chemistry; Tryptophan; Chloroform; Fluorophore; Photochemistry; Fluorescence; Quantum yield; Fluorescence spectroscopy; Proton NMR; Yield (engineering); Chromatography; Organic chemistry; Amino acid","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006973962,0.0002172456,0.0002612774,0.00001285744,0.0002770926,0.0000218539,0.0002457083,0.0002198952,0.001383586],"category_scores_gemma":[0.00004052733,0.0001436668,0.00009995885,0.0001414089,0.0003975554,0.00003323284,0.00004546063,0.0003093987,0.000005119693],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001278327,"about_ca_system_score_gemma":0.00001420026,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002095063,"about_ca_topic_score_gemma":0.000003813578,"domain_scores_codex":[0.9989387,0.0000135809,0.0003143407,0.0003242226,0.0001021074,0.0003070489],"domain_scores_gemma":[0.9989971,0.0001994322,0.0001693821,0.0004362795,0.00006436437,0.0001334421],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008232556,0.00009664957,0.0008477432,0.0001503555,0.0001202382,0.00000776015,0.00006208052,2.689448e-7,0.9979171,0.0002153145,0.000294922,0.0002052227],"study_design_scores_gemma":[0.0004771425,0.0000449954,0.00002505702,0.00004706188,0.00004537758,0.0002013898,0.0002762273,0.00008913701,0.969623,0.0003143463,0.02866795,0.0001883394],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9060593,0.0004487214,0.000004240933,0.0002242548,0.00001771934,0.00006402453,0.00002060245,0.00004993,0.09311119],"genre_scores_gemma":[0.9980334,0.0001764367,0.00003645249,0.00003307321,0.00008242455,0.00007154953,0.00001693343,0.00001387305,0.001535856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09197408,"threshold_uncertainty_score":0.9995293,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01242815374891207,"score_gpt":0.2093173686240791,"score_spread":0.196889214875167,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}