{"id":"W2048111771","doi":"10.1021/ja066450u","title":"Self-Assembly of Coordination Polymers:  Evidence for Dynamic Exchange between Oligomers in Solution and the Isolation of a Homochiral Decagold(I) Oligomer","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Oligomer; Isolation (microbiology); Polymer; Polymer chemistry; Self-assembly; Coordination polymer; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005800959,0.0001154542,0.0004114046,0.00002523525,0.00006156861,0.00001318596,0.0002998671,0.0000866088,0.000009323936],"category_scores_gemma":[0.000193064,0.00007408127,0.0003778858,0.0003704219,0.0003881611,0.0001052008,0.00005316663,0.0002298164,1.143012e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001495021,"about_ca_system_score_gemma":0.00005471385,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001798358,"about_ca_topic_score_gemma":0.000004966564,"domain_scores_codex":[0.9987867,0.00004844618,0.0006070724,0.0001255918,0.0002721519,0.0001600597],"domain_scores_gemma":[0.9973208,0.0009263806,0.001397467,0.0001996554,0.0001229525,0.00003268418],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008349761,0.00008876745,0.004500256,0.0001243776,0.00009773075,3.053279e-8,0.0003863343,0.00000910536,0.9905949,0.000124033,0.0002220172,0.003768935],"study_design_scores_gemma":[0.001691604,0.00004940106,0.0172835,0.0004182093,0.0004951783,0.00001055452,0.001034268,0.009861587,0.9675056,0.001283069,0.0001695321,0.0001974708],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991376,0.0009671151,0.004721002,0.002714358,0.00001792981,0.0001309741,0.0000124304,0.000005605074,0.00005458148],"genre_scores_gemma":[0.9943095,0.0002892936,0.005174765,0.00004632966,0.0001243678,0.00001429465,0.000002278162,0.00001317945,0.00002594563],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02308928,"threshold_uncertainty_score":0.3020946,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0141895711261229,"score_gpt":0.2713378956335371,"score_spread":0.2571483245074141,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}