{"id":"W2048170059","doi":"10.1016/j.tca.2012.08.002","title":"Electrode-spacer and other effects on the validity of the Kramers–Kronig relations and the fittings to the permittivity and electrical modulus spectra","year":2012,"lang":"en","type":"article","venue":"Thermochimica Acta","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"","keywords":"Kramers–Kronig relations; Electrode; Spectral line; Relaxation (psychology); Permittivity; Polarization (electrochemistry); Modulus; Chemistry; Analytical Chemistry (journal); Materials science; Dielectric; Physics; Physical chemistry; Composite material; Quantum mechanics; Optoelectronics; Refractive index","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005502999,0.0001862651,0.0002235003,0.00001589306,0.0004956117,0.0000472017,0.0002913333,0.00008397327,0.00006377223],"category_scores_gemma":[0.0002919509,0.00007545464,0.0001097366,0.000243581,0.0003290013,0.00003519723,0.0001313237,0.0005220383,0.000005686984],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003114485,"about_ca_system_score_gemma":0.00001763547,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003493241,"about_ca_topic_score_gemma":0.00002038979,"domain_scores_codex":[0.9988348,0.0001985682,0.000176063,0.000245061,0.0002114414,0.0003340036],"domain_scores_gemma":[0.9975473,0.001639119,0.0001343397,0.0005771599,0.00002061409,0.00008144567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008776193,0.0001157003,0.003733882,0.00001819421,0.000146679,4.704439e-8,0.001616334,0.000001072396,0.9710838,0.01918827,0.00143064,0.002577592],"study_design_scores_gemma":[0.0009744211,0.00008076509,0.03696675,0.00006261798,0.0006233446,0.00003112535,0.0001977782,0.002724981,0.9327946,0.009633657,0.01550541,0.000404563],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9718025,0.0002712141,0.00003881375,0.02323426,0.000009429504,0.000305971,0.000008658085,0.00002028327,0.004308908],"genre_scores_gemma":[0.997599,0.00007720976,0.00002660112,0.00113391,0.0001659102,0.0000782175,0.000001142126,0.00002078848,0.0008972269],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03828924,"threshold_uncertainty_score":0.3811894,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0103532129218153,"score_gpt":0.2230806043903363,"score_spread":0.212727391468521,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}