{"id":"W2048231100","doi":"10.1007/s10973-010-0758-0","title":"Thermal, UV and FTIR spectral studies of urea–thiourea zinc chloride single crystal","year":2010,"lang":"en","type":"article","venue":"Journal of Thermal Analysis and Calorimetry","topic":"Nonlinear Optical Materials Research","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Thiourea; Fourier transform infrared spectroscopy; Chemistry; Zinc; Crystal (programming language); Aqueous solution; Thermal decomposition; Analytical Chemistry (journal); Thermal analysis; Chloride; Urea; Single crystal; Exothermic reaction; Inorganic chemistry; Evaporation; Physical chemistry; Crystallography; Thermal; Organic chemistry; Chemical engineering; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001460987,0.000148918,0.0002720843,0.0002426688,0.000294796,0.0002050962,0.0003084413,0.0002511566,0.001682577],"category_scores_gemma":[0.0002930486,0.0001246581,0.0001449363,0.0004108666,0.0002170087,0.0001543392,0.000115211,0.0003010259,0.000161736],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002523164,"about_ca_system_score_gemma":0.0002485422,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00202839,"about_ca_topic_score_gemma":0.0024879,"domain_scores_codex":[0.9998424,0.000008316256,0.000009908316,0.00002807256,0.00009299426,0.00001829049],"domain_scores_gemma":[0.9997701,0.00005567742,0.00004932968,0.00001222819,0.00008865498,0.0000239883],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006547818,0.00001158679,0.0003000228,0.0000382633,0.000002503048,0.00006029498,0.00004115264,0.0001062131,0.9980939,0.00004234227,0.00005670805,0.001181575],"study_design_scores_gemma":[0.000007712494,0.000109363,0.008689565,0.000006394467,0.000009345298,0.0001293196,0.00007829529,0.001421856,0.9887304,0.00001706562,0.0007908212,0.00000995189],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973015,0.0006084764,0.0007277444,0.00003735346,0.00001512178,0.000006484561,0.0002460978,0.00002401814,0.001033217],"genre_scores_gemma":[0.9967338,0.0002757571,0.001191772,0.00001881069,0.000004289844,0.00001037305,0.0002659942,0.00001396999,0.00148519],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00202839,"threshold_uncertainty_score":0.005628765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02519231810721275,"score_gpt":0.3084258157115646,"score_spread":0.2832334976043519,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}