{"id":"W2048322550","doi":"10.1021/jp000025k","title":"A Determination of the Bond Dissociation Energy (<i>D</i><sub>0</sub>(H−SH)):  Threshold Ion-Pair Production Spectroscopy (TIPPS) of a Triatomic Molecule","year":2000,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":84,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Triatomic molecule; Chemistry; Dissociation (chemistry); Polyatomic ion; Atomic physics; Ion; Molecule; Spectroscopy; Bond-dissociation energy; Fragmentation (computing); Diatomic molecule; Photodissociation; Excitation; Physics; Photochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001473382,0.0002203467,0.000151388,0.0003811807,0.0003191722,0.0002029366,0.0004140202,0.00043336,0.001412894],"category_scores_gemma":[0.0004334751,0.000161552,0.0001070493,0.0002076089,0.0005034783,0.0003444466,0.0003498891,0.0006544489,0.00018547],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001522842,"about_ca_system_score_gemma":0.0001213042,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001821341,"about_ca_topic_score_gemma":0.000208183,"domain_scores_codex":[0.9999065,0.000011306,0.000003193502,0.00002372713,0.00004068909,0.0000145494],"domain_scores_gemma":[0.9997823,0.00008181591,0.00005189978,0.0000201702,0.00003690371,0.00002696359],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004699741,0.00001183868,0.00168905,0.00004637587,0.000006338494,0.00008555131,0.00006769686,0.000206982,0.9948851,0.0005360051,0.00006673235,0.002351375],"study_design_scores_gemma":[0.000007814135,0.0001579591,0.005241289,0.000006121738,0.00001213973,0.0003435485,0.00006963766,0.004359042,0.9887273,0.0003707617,0.0006934345,0.00001105382],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9871281,0.0003882972,0.009969369,0.0001017929,0.00001622957,0.00001118163,0.0001272128,0.00005737432,0.002200456],"genre_scores_gemma":[0.993948,0.0001478745,0.005477785,0.00002043111,0.000006700262,0.000007816781,0.00006318567,0.000008643753,0.0003195854],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001412894,"threshold_uncertainty_score":0.004726589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004737158930735113,"score_gpt":0.2288354493303983,"score_spread":0.2240982903996632,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}