{"id":"W2048634776","doi":"10.1021/ja034807d","title":"A Photochromic, Electrochromic, Thermochromic Ru Complexed Benzannulene:  an Organometallic Example of the Dimethyldihydropyrene−Metacyclophanediene Valence Isomerization","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Photochromism; Chemistry; Photochemistry; Isomerization; Visible spectrum; Diarylethene; Electrochromism; Irradiation; Thermochromism; Photostationary state; Photodarkening; Photocatalysis; Valence (chemistry); Azobenzene; Photoisomerization; Catalysis; Organic chemistry; Physical chemistry; Polymer; Electrode; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009115028,0.0001831667,0.0001995199,0.00009631085,0.0001609727,0.0003310229,0.0003297926,0.0003361572,0.00130076],"category_scores_gemma":[0.0001771435,0.0001461778,0.0001357715,0.00009999266,0.0002631771,0.0002423022,0.000190387,0.0004703406,0.0003110043],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000252505,"about_ca_system_score_gemma":0.0001176695,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002863125,"about_ca_topic_score_gemma":0.0005426446,"domain_scores_codex":[0.9998983,0.00001689835,0.000004678089,0.00002719448,0.00003195882,0.00002104156],"domain_scores_gemma":[0.9999394,0.00001518612,0.00001207413,0.00001244717,0.000006101565,0.0000148],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004863115,0.00002736776,0.00004277873,0.00006597357,0.000003806236,0.0001447736,0.00004844748,0.0001114718,0.995895,0.0008137517,0.00006862103,0.002729399],"study_design_scores_gemma":[0.0000216102,0.0002414201,0.0003543954,0.000002905704,0.000004845249,0.0004588794,0.00001083898,0.0003959589,0.9947114,0.0001023599,0.003686506,0.000008908437],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9815611,0.001633703,0.007668701,0.0001437447,0.00007644798,0.00008251025,0.0001881093,0.0002134731,0.00843219],"genre_scores_gemma":[0.9893807,0.0007365119,0.005705466,0.00004108241,0.000009639528,0.00002263552,0.00009342839,0.00002506627,0.003985369],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00130076,"threshold_uncertainty_score":0.004351437,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01192086476830565,"score_gpt":0.2376684640169111,"score_spread":0.2257475992486054,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}