{"id":"W2048634776","doi":"10.1021/ja034807d","title":"A Photochromic, Electrochromic, Thermochromic Ru Complexed Benzannulene:  an Organometallic Example of the Dimethyldihydropyrene−Metacyclophanediene Valence Isomerization","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Photochromism; Chemistry; Photochemistry; Isomerization; Visible spectrum; Diarylethene; Electrochromism; Irradiation; Thermochromism; Photostationary state; Photodarkening; Photocatalysis; Valence (chemistry); Azobenzene; Photoisomerization; Catalysis; Organic chemistry; Physical chemistry; Polymer; Electrode; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008225342,0.0003415642,0.0008383249,0.00002592574,0.0002508837,0.00005554437,0.001894232,0.0001113062,0.0004051666],"category_scores_gemma":[0.0002837912,0.0002055405,0.0007571865,0.0008096565,0.001622738,0.0002767744,0.0002188719,0.0005131366,0.000006499774],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000308998,"about_ca_system_score_gemma":0.0004249338,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000135711,"about_ca_topic_score_gemma":0.000001485155,"domain_scores_codex":[0.9970949,0.0002989031,0.0009090116,0.0004027474,0.0007660316,0.0005283767],"domain_scores_gemma":[0.9964743,0.000161256,0.002050918,0.0008755491,0.0002526927,0.0001852689],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006533982,0.0002312207,0.000397142,0.00003272063,0.00007300966,8.818565e-7,0.0004655768,0.00004735416,0.9981537,0.00004350374,0.0004045743,0.00008492813],"study_design_scores_gemma":[0.000646857,0.0001095548,0.001730158,0.00006405169,0.0001326656,0.0001538687,0.0002606286,0.0001671207,0.9956825,0.000542782,0.0002632985,0.0002465336],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983917,0.0003058327,0.0005064943,0.0001594677,0.0002438308,0.0002734138,0.000030723,0.00002155062,0.00006695034],"genre_scores_gemma":[0.994562,0.0001895013,0.004450494,0.0004988694,0.0001767528,0.00001027257,0.000003401839,0.00004369191,0.00006497447],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003944,"threshold_uncertainty_score":0.8381698,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01192086476830565,"score_gpt":0.2376684640169111,"score_spread":0.2257475992486054,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}