{"id":"W2048752786","doi":"10.1016/j.chroma.2010.10.057","title":"Polydimethylsiloxane-based permeation passive air sampler. Part II: Effect of temperature and humidity on the calibration constants","year":2010,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Advanced Chemical Sensor Technologies","field":"Engineering","cited_by":32,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Waterloo","funders":"","keywords":"Permeation; Chemistry; Polydimethylsiloxane; Humidity; Activation energy; Chromatography; Analytical Chemistry (journal); Analyte; Relative humidity; Membrane; Water vapor; Calibration; Vapor pressure; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001210342,0.0008629445,0.0008251565,0.0003762518,0.0004686686,0.0005921521,0.001234944,0.0008605287,0.003208442],"category_scores_gemma":[0.002483819,0.0006923335,0.0005449522,0.0004376462,0.000425135,0.0007516329,0.0005373831,0.0009645246,0.002408136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004444755,"about_ca_system_score_gemma":0.0009229665,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001523542,"about_ca_topic_score_gemma":0.001938819,"domain_scores_codex":[0.9988525,0.0002179508,0.00009872379,0.0003053248,0.0004612268,0.00006436578],"domain_scores_gemma":[0.9990622,0.0005144445,0.00006717685,0.0001351755,0.0001855794,0.00003545745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001129086,0.0001854728,0.001601449,0.0004573764,0.00009673508,0.00004216168,0.00007753573,0.0004883907,0.9510312,0.0002633487,0.001090701,0.04353656],"study_design_scores_gemma":[0.00002876731,0.000234042,0.002589773,0.00001110258,0.00004975535,0.0001628424,0.00001326177,0.002537187,0.9896912,0.00007490426,0.00458923,0.00001781436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5425466,0.01398845,0.4248528,0.0005812681,0.001001009,0.001665168,0.00510958,0.004366399,0.005888664],"genre_scores_gemma":[0.7331392,0.01115067,0.2218457,0.001252411,0.0001965098,0.002010857,0.007023932,0.0009010297,0.02247985],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003208442,"threshold_uncertainty_score":0.01073325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004710636859051142,"score_gpt":0.206947386998461,"score_spread":0.2022367501394098,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}