{"id":"W2048795907","doi":"10.1021/jp1092898","title":"Local Geometry of Electromagnetic Fields and Its Role in Molecular Multipole Transitions","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Office of Naval Research; Natural Sciences and Engineering Research Council of Canada; Defense Advanced Research Projects Agency","keywords":"Multipole expansion; Superposition principle; Physics; Polarization (electrochemistry); Plane wave; Electromagnetic field; Electromagnetic radiation; Near and far field; Plane (geometry); Monochromatic color; Field (mathematics); Geometry; Classical mechanics; Computational physics; Optics; Quantum mechanics; Mathematics; Chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006038264,0.00008092923,0.0001859909,0.00001087929,0.00002457945,0.000002418293,0.0001149521,0.00002216642,0.0000988574],"category_scores_gemma":[0.000005573213,0.00005588548,0.00008233207,0.00009642386,0.00008634822,0.00003376378,0.0000218376,0.0002507498,6.497465e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007419947,"about_ca_system_score_gemma":0.00001400089,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002921966,"about_ca_topic_score_gemma":3.934279e-7,"domain_scores_codex":[0.9995337,0.0000160385,0.0001729071,0.00005456869,0.00009671936,0.0001260503],"domain_scores_gemma":[0.9997073,0.00005630322,0.00009111249,0.00006370104,0.00003770647,0.0000438718],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005753957,0.0002453005,0.000136965,0.00001755046,0.00004602302,0.0000015966,0.0007757564,0.00003133963,0.9977157,0.0006520685,0.000006564837,0.0003135723],"study_design_scores_gemma":[0.000331099,0.0001182874,0.0005378957,0.00002570346,0.00005326157,0.000003715105,0.0005479229,0.0007534512,0.9900942,0.007470322,0.000005785297,0.00005839911],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963725,0.0003406727,0.0009876279,0.0000644597,0.000003887386,0.00002847453,0.000004567054,0.000001673891,0.002196163],"genre_scores_gemma":[0.9998567,0.000006251557,0.00004425201,0.000008594681,0.0000661314,0.000001427447,5.562755e-7,0.000004617108,0.00001147309],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007621566,"threshold_uncertainty_score":0.2278944,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00616306929257758,"score_gpt":0.2204237946465653,"score_spread":0.2142607253539877,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}