{"id":"W2048971414","doi":"10.1039/b513624e","title":"On the role of alkylcobalamins in the vitamin B<sub>12</sub>-catalyzed reductive dehalogenation of perchloroethylene and trichloroethylene","year":2005,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Trichloroethylene; Halogenation; Catalysis; Reactivity (psychology); Chemistry; Organic chemistry; Reductive elimination; Photochemistry; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002611597,0.0004413156,0.000160623,0.0001698682,0.0004730334,0.0003374797,0.0003701033,0.0002944811,0.002227454],"category_scores_gemma":[0.000279224,0.0001249154,0.0001516307,0.0001362414,0.0005462926,0.0003744881,0.0002783659,0.0003399788,0.0003886608],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004268104,"about_ca_system_score_gemma":0.0003049614,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002091299,"about_ca_topic_score_gemma":0.001456723,"domain_scores_codex":[0.9999293,0.00002047963,0.000002148224,0.00001044354,0.00001223347,0.00002537628],"domain_scores_gemma":[0.9998372,0.00009658515,0.00002137464,0.00001376508,0.00002019099,0.00001098116],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001911033,0.0001275227,0.002421571,0.0006654386,0.00006570797,0.00202779,0.001174229,0.02025336,0.8548575,0.07871094,0.0003409283,0.0374439],"study_design_scores_gemma":[0.00005181726,0.0007196643,0.002848793,0.00006509917,0.00006765797,0.0007791533,0.0007887652,0.02363605,0.9509464,0.01186795,0.008195465,0.00003316463],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9727387,0.00259376,0.01129089,0.0003434813,0.00001434683,0.00002765798,0.00004888299,0.00002788905,0.01291433],"genre_scores_gemma":[0.9936016,0.002386315,0.00218396,0.00002550213,0.000004170897,0.00001149931,0.00003053003,0.000008132878,0.001748261],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002227454,"threshold_uncertainty_score":0.007451594,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01111208720134245,"score_gpt":0.2423218868524352,"score_spread":0.2312097996510928,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}