{"id":"W2049210618","doi":"10.1016/j.bmcl.2005.03.108","title":"A micromethod for the stereochemical analysis of fatty acid desaturase-mediated sulfoxidation reactions","year":2005,"lang":"en","type":"article","venue":"Bioorganic & Medicinal Chemistry Letters","topic":"Molecular spectroscopy and chirality","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"Health Canada; Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Reagent; Fatty acid; Analyte; Organic chemistry; Stereochemistry; Chromatography; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009927636,0.000588677,0.0004482771,0.0009727863,0.0006267596,0.0003627955,0.0007365591,0.0006225238,0.001919259],"category_scores_gemma":[0.0006606798,0.0003854349,0.0003370868,0.000553277,0.0003858853,0.0003788329,0.0005651116,0.001020656,0.001044157],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004589823,"about_ca_system_score_gemma":0.001375989,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008767687,"about_ca_topic_score_gemma":0.002069937,"domain_scores_codex":[0.999286,0.0001165284,0.00005989014,0.0001890025,0.0002614033,0.00008719367],"domain_scores_gemma":[0.9994537,0.0001234348,0.0000597929,0.0001520645,0.0001526185,0.0000583352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007029607,0.00005136828,0.000441398,0.00006830777,0.00001125709,0.00002978186,0.00002298142,0.0001349751,0.9734184,0.001221526,0.0002593594,0.0242704],"study_design_scores_gemma":[0.00001394173,0.000211165,0.000732824,0.000006721639,0.00001378774,0.0001542532,0.00001606683,0.001718761,0.9923075,0.0003726579,0.00443894,0.00001328765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"methods","genre_scores_codex":[0.133398,0.001785795,0.8543927,0.0001879397,0.000266896,0.0006586389,0.002346789,0.002303967,0.004659285],"genre_scores_gemma":[0.3118249,0.00235555,0.6724372,0.0002017683,0.00005979268,0.001696454,0.002133816,0.0001894341,0.009101158],"genre_candidate":"methods","genre_consensus":"methods","teacher_disagreement_score":0.001919259,"threshold_uncertainty_score":0.006420612,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01414249710017801,"score_gpt":0.2699123049163552,"score_spread":0.2557698078161771,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}