{"id":"W2049297611","doi":"10.1021/ja907519c","title":"Highly Birefringent Cyanoaurate Coordination Polymers: The Effect of Polarizable C−X Bonds (X = Cl, Br)","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Terpyridine; Chemistry; Crystallography; Birefringence; Supramolecular chemistry; Polymer; Crystal structure; Stereochemistry; Metal; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004836926,0.0001792278,0.0004428774,0.00001245555,0.0001487277,0.00003911446,0.0007569339,0.00009732298,0.0001363189],"category_scores_gemma":[0.0001832011,0.00009397383,0.0006544443,0.000437808,0.0002693857,0.00007064691,0.00007966411,0.0005935205,0.00000297112],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001358717,"about_ca_system_score_gemma":0.00005246316,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003221665,"about_ca_topic_score_gemma":1.2668e-7,"domain_scores_codex":[0.9985622,0.00006298936,0.0005256612,0.0001538883,0.0004546445,0.0002405787],"domain_scores_gemma":[0.997718,0.000401534,0.001251601,0.0004448593,0.00009103508,0.00009292163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000038059,0.00007596194,0.0004722833,0.00001650493,0.0001321756,2.40336e-7,0.00008909657,0.00001881916,0.983151,0.00006789847,0.00553222,0.0104057],"study_design_scores_gemma":[0.0002890755,0.00009650869,0.0004648553,0.00007268353,0.000192481,0.00002671252,0.000172476,0.0004294426,0.9929219,0.0001942367,0.005028322,0.0001113168],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986608,0.0004325836,0.0004790474,0.01162186,0.00004537749,0.00006690352,0.00001124011,0.00001608142,0.0007189593],"genre_scores_gemma":[0.9976367,0.00008568233,0.001007831,0.000667128,0.0003330349,0.000003502357,0.000001676619,0.00001757906,0.0002468611],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01102875,"threshold_uncertainty_score":0.3832142,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006421886081031581,"score_gpt":0.2376562052352049,"score_spread":0.2312343191541733,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}